一种脱硫废液转硫铵催化剂的制备方法

CN121155685BActive Publication Date: 2026-07-17JIANGXI JEFF ENVIRONMENTAL PROTECTION TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGXI JEFF ENVIRONMENTAL PROTECTION TECH CO LTD
Filing Date
2025-09-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In traditional preparation methods, metal ion precipitation is incomplete, leading to the loss of active components. Improper control of the precipitant addition method and reaction conditions affects catalyst performance. Furthermore, the drying and calcination processes are difficult to control precisely, resulting in uneven particle size and a reduction in the number of active sites.

Method used

The method employs air flotation to remove impurities, ultrasonic-assisted precipitation, spray drying, and microwave calcination. By controlling the pH value and temperature, the ultrasonic cavitation effect is used to promote the contact between the precipitant and metal ions. Spray drying increases the contact area between the liquid and hot air, and microwave calcination promotes uniform heating and crystallization, avoiding agglomeration.

Benefits of technology

It improves the recovery rate and purity of active components, produces precipitates with uniform particle size distribution, increases the specific surface area and number of active sites of the catalyst, and enhances catalytic performance and stability.

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Abstract

本发明属于脱硫废液转硫铵催化剂制备技术领域,具体涉及一种脱硫废液转硫铵催化剂的制备方法,包括以下步骤:第一步、预处理:采用气浮法去除脱硫脱酸的废液中含有焦油、悬浮物、胶体杂质,本发明通过采用分步沉淀结合超声波辅助的方式,分步沉淀利用了不同金属离子在特定pH值下沉淀的特性,通过精确控制pH值,让金属离子依次沉淀,避免相互干扰,从而提高活性组分的回收率和纯度,超声波的空化效应产生局部高温、高压以及强烈的冲击波和微射流,能够打破溶液中的扩散层,加速沉淀剂与金属离子的反应速率,同时阻止沉淀物的团聚生长,使得生成的沉淀物具有更均匀的粒径分布和更高的比表面积,为后续制备高性能催化剂奠定基础。
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