一种高熵稀土掺杂WC硬质合金及其制备方法和应用

By using wet co-deposition and magnetron sputtering techniques, atomic-level dispersion of rare earth elements and uniform distribution of high-entropy rare earth nanoparticles in WC alloys were achieved, solving the problem of limited improvement in hardness and strength of rare earth-doped WC alloys and preparing high-performance WC cemented carbides.

CN121178840BActive Publication Date: 2026-07-17INSTITUTE OF MATERIALS & INTELLIGENT MANUFACTURING JIANGXI ACADEMY OF SCIENCES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INSTITUTE OF MATERIALS & INTELLIGENT MANUFACTURING JIANGXI ACADEMY OF SCIENCES
Filing Date
2025-09-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing rare earth-doped WC alloys, the rare earth elements are not evenly dispersed, resulting in limited improvement in hardness and mechanical properties. Therefore, the preparation method needs to be improved.

Method used

The precursor was prepared by wet co-deposition. Through steps such as calcination, reduction, carbonization and magnetron sputtering Co deposition, the atomic-level dispersion of rare earth elements and the uniform distribution of high-entropy rare earth nanoparticles in WC crystals were achieved. Combined with the core-shell structure, the hardness and strength of the alloy were improved.

Benefits of technology

The prepared high-entropy rare-earth-doped WC cemented carbide has a hardness of over 93.9 HRA and a bending strength of over 2980 MPa, which significantly improves the mechanical properties of the alloy.

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Abstract

本发明提供了一种高熵稀土掺杂WC硬质合金及其制备方法和应用,属于合金技术领域。本发明采用湿法共沉积制备前驱体,相比于球磨混合,能够实现原子级分散,避免稀土偏聚,高熵稀土纳米颗粒分布于WC晶内且钉扎在WC晶界,阻碍位错移动,同时采用高熵稀土掺杂WC,高熵稀土中各元素协同作用,提高合金硬度和强度,采用磁控溅射镀Co,相比于化学镀,能够提高界面结合强度并避免引入杂质,进一步提高合金的硬度和强度。实施例的结果显示,本发明制备的高熵稀土掺杂WC硬质合金的硬度在93.9HRA以上,抗弯强度在2980MPa以上。
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