一种从还原焙烧深海锰结核水浸提取锰的方法

By using a reduction roasting and water leaching method with a mixed flux of ammonium sulfate and ammonium acetate or ammonium propionate in deep-sea manganese nodules, the problem of low manganese extraction efficiency in deep-sea manganese nodules has been solved, realizing an efficient, low-energy-consumption, and environmentally friendly manganese extraction process to obtain high-purity manganese products.

CN121183114BActive Publication Date: 2026-07-17CHONGQING YUEJIA NEW MATERIALS CO LTD +2
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-09-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for efficiently extracting manganese from deep-sea manganese nodules, and conventional methods are energy-intensive, costly, and environmentally damaging, making them unsuitable for industrial applications.

Method used

A mixed flux of 70% ammonium sulfate and 30% ammonium acetate or ammonium propionate is used for reduction roasting under inert gas protection. High-valence manganese is reduced to low-valence manganese through low-temperature roasting, and manganese is extracted by sulfation reaction. Impurities are separated by water leaching to obtain high-purity manganese sulfate or manganese tetroxide.

Benefits of technology

It achieves efficient extraction of manganese from deep-sea manganese nodules with a recovery rate of over 98%, significantly reduces energy consumption, extends equipment life, is environmentally friendly, effectively removes impurities, and achieves high purity.

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Abstract

本发明公开了一种还原焙烧深海锰结核水浸提取锰的方法,将深海锰结核烘干粉碎、筛分后与所述的熔剂混合均匀,惰性气体保护下在管式炉中升温至200℃,恒温焙烧,升温至290℃,恒温焙烧,然后升温至640℃,恒温焙烧,焙烧完成后自然冷却到室温,加入去离子水于室温从焙烧样品中浸出硫酸锰,过滤分离,将滤液分级净化除杂后,加入碳酸氢铵将硫酸锰转变为碳酸锰,过滤用去离子水洗涤,煅烧,得到四氧化三锰。利用熔剂在惰性气体保护下形成还原气氛,充分利用深海锰结核中的锰源,将高价锰还原为低价锰,利用低价锰进行硫酸化反应,所形成的可溶性硫酸锰通过去离子水浸,从而从深海锰结核中高效提取锰。
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Citation Information

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