一种本征型低介电聚酰亚胺薄及其制备方法和应用

By introducing branched organic fillers into polyimide films and controlling the proportion of raw materials, polyimide films with low dielectric constants can be prepared, solving the problems of transmission loss and waveform distortion in high-frequency environments, achieving a reduction in dielectric constant and an improvement in performance, and making them suitable for flexible circuit boards for 5G base stations.

CN121226802BActive Publication Date: 2026-07-17HARBIN UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HARBIN UNIV OF SCI & TECH
Filing Date
2025-10-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyimide films have a high dielectric constant, which makes it difficult to meet the requirements of 5G communication for low dielectric materials, especially in high-frequency environments where transmission loss and waveform distortion are severe.

Method used

By introducing branched organic fillers and controlling the proportion of raw materials, intrinsic low-dielectric polyimide films are prepared, reducing molecular polarizability and the number of polarized molecules, increasing the molecular chain spacing, and inhibiting the formation of charge-transfer complexes.

Benefits of technology

It achieves a dielectric constant reduction to 2.4-2.5 while maintaining good thermal stability and mechanical properties, making it suitable for flexible circuit boards for 5G base stations.

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Abstract

本发明公开了一种本征型低介电聚酰亚胺薄及其制备方法和应用;属于5G通讯基站技术领域。本发明通过支化结构在聚酰亚胺分子中能够提高其自由体积从而得到高性能、低介电常数的效果。本发明方法:将三元胺,粘合剂、酯类化合物和封端剂加入溶剂中,惰性气体保护下加热搅拌至少6h,用无水乙醇洗掉多余溶剂,烘干,得到支化有机填料;将支化有机填料加入溶剂中,搅拌至溶液澄清后加入二胺,搅拌均匀,将二酐以等量分次的方式加入,然后在冰水浴中搅拌至爬杆,得到成膜液;将成膜液成膜处理,得到0.3mm‑2mm的液膜,液膜进行程序化升温后,冷却至室温,得到所述薄膜。本方法废液易于处理,能源消耗少,可实现连续化大规模生产。
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