一种高倍率复合硅基负极材料及其制备方法和应用

By preparing a high-rate composite silicon-based anode material with a core-shell structure, the core is a porous composite framework of fluorinated oxide solid electrolyte and carbon, and silicon nanomaterials are deposited on the surface and coated with fluorinated oxide solid electrolyte and carbon. This solves the problems of poor rate performance and low first-cycle coulombic efficiency of silicon-based anode materials and improves the overall performance of lithium-ion batteries.

CN121260765BActive Publication Date: 2026-07-17LIYANG TIANMU PILOT BATTERY MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LIYANG TIANMU PILOT BATTERY MATERIAL TECH CO LTD
Filing Date
2025-09-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing silicon-based anode materials suffer from poor rate performance and low first-cycle coulombic efficiency, making it difficult to meet the requirements of high energy density and safety performance, especially in lithium-ion batteries.

Method used

The high-rate composite silicon-based anode material has a core-shell structure. The core is a porous composite framework of fluorinated oxide solid electrolyte and carbon. Silicon nanomaterials are deposited on the surface and pore walls. The outer layer is coated with fluorinated oxide solid electrolyte and carbon to form stable FC bonds, which improves conductivity and mechanical strength.

Benefits of technology

It improves the rate performance and first-cycle coulombic efficiency of lithium-ion batteries, enhances the structural strength and compaction density of materials, improves the conductivity and ion conduction ability of materials, and solves the performance bottleneck of silicon-based anode materials in lithium-ion batteries.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及一种高倍率复合硅基负极材料及其制备方法和应用,高倍率复合硅基负极材料包括:硅碳复合材料,包覆在硅碳复合材料的外表面的复合包覆层,分散于硅碳复合材料和复合包覆层中的氟化锂;硅碳复合材料包括固态电解质多孔碳复合骨架和沉积生长在固态电解质多孔碳复合骨架的表面和孔壁上的硅纳米材料;固态电解质多孔碳复合骨架是通过将第一氟化氧化物固态电解质的原料与碳源材料经过高温处理、物理活化造孔后得到;第一氟化氧化物固态电解质的氟原子与固态电解质多孔碳复合骨架中的碳原子形成F‑C键;复合包覆层包括第二氟化氧化物固态电解质和包覆碳;将高倍率复合硅基负极材料应用于锂电池中,可以提高锂电池的倍率性能和首周库伦效率。
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