一种具有低衰减特性的小粒径铈锆固溶体及其制备方法

By adjusting the pH value of the acidic cerium and zirconium solution, the preparation process of cerium-zirconium solid solution was controlled, which solved the problems of insufficient low attenuation and anti-sintering properties. A cerium-zirconium solid solution with low attenuation and small particle size was prepared, which improved the purification performance of the catalyst.

CN121288802BActive Publication Date: 2026-07-17JIANGMEN KANHOO IND CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGMEN KANHOO IND CO LTD
Filing Date
2025-09-22
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to prepare cerium-zirconium solid solutions that combine low decay and anti-sintering properties, resulting in low utilization efficiency of precious metals and insufficient catalyst purification performance.

Method used

By adjusting the pH values ​​of acidic solutions of cerium and zirconium respectively, the precipitation rate of cerium ions and the formation of zirconium particles are controlled to form a uniformly mixed suspension. Then, an alkaline solution is added to precipitate and calcined to prepare a cerium-zirconium solid solution.

Benefits of technology

While maintaining a high fresh specific surface area, it significantly improves the anti-sintering ability of oxygen storage materials, obtains excellent characteristics of low attenuation and small particle size, and enhances the overall performance of the catalyst.

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Abstract

本发明属于催化剂领域,公开了一种具有低衰减特性的小粒径铈锆固溶体及其制备方法,包括以下步骤:制备含铈离子的金属盐溶液A,然后将金属盐溶液A的pH值调至1.5‑3.0;制备含锆离子和除了铈以外的至少一种稀土离子的金属盐溶液B,然后将金属盐溶液B的pH值调至低于金属盐溶液A的pH值;将溶液A和溶液B混合,得到溶液C;往溶液C中滴加碱性溶液,使其完全沉淀,得到沉淀物;将沉淀物过滤并洗涤,至洗涤液pH为7,过滤得到滤渣;将得到的滤渣进行焙烧,得到所述的铈锆固溶体;利用该方法,可以在保证较高新鲜比表面积的同时,使储氧材料的抗烧结能力大幅提高,从而得到同时拥有了低衰减和小粒径的优异特性的铈锆固溶体。
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