一种具有复合结构的固态电池正极极片及制备方法和应用

By employing particle size gradient design and a two-step molding process, a multi-scale composite solid-state battery cathode sheet was constructed, which solved the problems of poor interfacial contact between the electrolyte and the electrode and lithium dendrite growth in solid-state batteries. This improved ionic conductivity and interfacial stability, and enhanced the cycle performance of lithium batteries.

CN121306937BActive Publication Date: 2026-07-17LIYANG TIANMU PILOT BATTERY MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LIYANG TIANMU PILOT BATTERY MATERIAL TECH CO LTD
Filing Date
2025-10-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing solid-state batteries, poor solid-solid interface contact between the electrolyte and the electrode, high interface impedance, severe interfacial side reactions, and easy growth of lithium dendrites lead to low ion transport efficiency and interface instability, affecting battery performance.

Method used

By employing a particle size gradient design and a two-step molding process, the positive electrode active material is mechanically coated with an oxyfluoride solid electrolyte to construct a preliminary ion conduction and interface protection layer. Then, a nano-scale oxyfluoride solid electrolyte and in-situ polymer composite slurry are coated on the outer layer to form a solid-state battery positive electrode sheet with a multi-scale, functionally gradient composite structure.

Benefits of technology

It significantly improves the ionic conductivity and interfacial stability of the positive electrode of solid-state batteries, suppresses side reactions, and enhances the cycle performance and mechanical reliability of lithium batteries.

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Abstract

本发明涉及一种具有复合结构的固态电池正极极片及制备方法和应用,固态电池正极极片包括:集流体,附着于集流体的一侧表面的复合正极涂层,以及附着于复合正极涂层的复合聚合物涂层;复合正极涂层包括:正极活性材料、第一氧氟化物固态电解质、粘结剂和导电剂;复合聚合物涂层包括:原位聚合的三维网状结构的聚合物,以及填充于三维网状结构的空隙中的锂盐和第二氧氟化物固态电解质;聚合物是通过热引发剂引发聚合物单体发生原位聚合而形成;复合正极涂层的空隙中浸入有复合聚合物涂层。本发明的固态电池正极极片具有高离子电导、高界面稳定及高机械可靠性,将其用于固态锂电池中,可以提高固态锂电池的循环性能。
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