Preparation method of CdTe quantum dot sensitized BiOBr-SnO2 photoelectric gate, sensor and application

CN121310786BActive Publication Date: 2026-08-28JIANGSU UNIV
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Patent Information

Application Number
CN202511396187.6
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-09-26
Publication Date
2026-08-28
Estimated Expiration
2045-09-26

AI Technical Summary

Technical Problem

[0002]作为一种典型的抗生素类新型污染物,四环素(TC)滥用导致大量TC抗生素经粪肥施用与污水灌溉等途径进入土壤,对生态环境安全和人类健康构成严重威胁

Benefits of technology

(1)本发明通过设计三元复合栅极,制备了CdTe QDs/BiOBr-SnO2/ITO光电复合栅极,适当掺杂比例的BiOBr-SnO2异质结构,促进更多有效的载流子参与光电转换过程;进一步经过CdTe QDs敏化,所得到的三元复合栅极相较于BiOBr-SnO2的沟道电流有大幅提升,且其OPECT调控能力明显高于BiOBr-SnO2光电栅极。

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Abstract

The application provides a preparation method of a CdTe quantum dot sensitized BiOBr-SnO2 photoelectric grid, a sensor and application, and belongs to the technical field of nanomaterials, organic photoelectric chemical transistor (OPECT) aptamer sensing and agricultural environment monitoring. The method comprises the following steps: (1) preparing nanosheet-shaped BiOBr through a hydrothermal method; (2) preparing SnO2 nanoparticles through a hydrothermal method; (3) mixing SnO2 and BiOBr suspending liquid according to a volume ratio of 3:1 to prepare a SnO2-BiOBr heterojunction; (4) preparing CdTe quantum dots by reacting NaBH4 and Te powder to generate NaHTe precursor, and then refluxing the source at 100 DEG C under the condition of pH 10-11 for 7 hours; and (5) sequentially modifying the SnO2-BiOBr heterojunction and the CdTe quantum dots on the surface of an ITO electrode to obtain a CdTe QDs / BiOBr-SnO2 / ITO ternary composite photoelectric grid. The sensor constructed by the application can be used for detecting TC in actual soil samples, and exhibits good anti-interference performance and reliability; and the design idea proposed in the application can be used for developing a sensing method for detecting other antibiotics, and has a good application prospect.
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Citation Information

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