一种锂云母提锂卤水除氟氯的方法

By using a combination of trioctylmethylammonium sulfate and trioctylmethylammonium chloride as extractants and isooctyl alcohol as a diluent in lithium extraction brine from lepidol, the problem of poor chlorine and fluoride removal in lepidol brine from lepidol was solved, achieving highly selective and low-loss chlorine and fluoride removal and improving the quality of lithium products.

CN121317823BActive Publication Date: 2026-07-17FENGCHENG JIULING LITHIUM IND CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
FENGCHENG JIULING LITHIUM IND CO LTD
Filing Date
2025-10-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies have limited effectiveness in removing chlorine and fluoride from lithium brine extracted from lepidolite, and introduce other impurity ions, making it difficult to meet increasingly stringent quality requirements for lithium products.

Method used

Trioctylmethylammonium sulfate and trioctylmethylammonium chloride were used as a combined extractant, and isooctyl alcohol was used as a diluent. After pretreatment of lithium brine from lepidolite by extraction, the pH value was adjusted to 5-5.5. The formation of BF4- was used to improve the removal rate of fluoride and chlorine, and the extractant was regenerated by back-extraction.

Benefits of technology

This method achieves highly selective removal of chlorine and fluoride from lithium brine extracted from lepidolite, reduces lithium loss rate, improves the purity and quality of lithium products, and reduces equipment corrosion risk.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及锂云母提取技术领域,具体涉及一种锂云母提锂卤水除氟氯的方法。一种锂云母提锂卤水除氟氯的方法,述方法包括以下步骤:S1、预处理:向锂云母提锂卤水中加入硼酸,充分混合均匀后加入硫酸溶液调节卤水pH为5‑5.5得到预处理卤水;S2、除氟氯:将预处理卤水与除氟氯萃取剂混合后进行萃取处理,分离出水相和油相,所述水相即为去除氟氯后的提锂卤水,所述除氟氯萃取剂包括组合物萃取剂和异辛醇,所述组合萃取剂由三辛基甲基硫酸铵和三辛基甲基氯化铵组成。该方法对锂云母提锂卤水中氯和氟同时具备高选择性和去除率,且锂损率较低。
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