一种基于改性聚醚的破乳剂及其制备方法和应用

By combining oleate-modified polyether with multifunctional synergistic additives, the problems of ion interference and oil droplet aggregation of modified polyether demulsifiers in complex industrial quench water systems are solved, achieving efficient demulsification and low residual oil discharge, and adapting to multiple working conditions.

CN121360397BActive Publication Date: 2026-07-17JIANGSU TAIHU CHEM

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGSU TAIHU CHEM
Filing Date
2025-12-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing modified polyether demulsifiers have weak resistance to ion interference, low oil droplet coalescence efficiency, and poor compatibility with auxiliary functional components when treating complex industrial quench water systems, resulting in low demulsification efficiency and easy secondary emulsification.

Method used

The technology employs a combination of oleo-esterified modified polyether and multifunctional synergistic additives. Through an integrated crosslinking-chelation-synergistic design, it combines phosphonamide groups to chelate metal ions, a mild crosslinking network to promote oil droplet aggregation, and intermolecular multi-force synergistic demulsification. Combined with directional esterification and azeotropic dehydration processes, it enhances interfacial activity and demulsification efficiency.

Benefits of technology

Under hard water conditions, the demulsification efficiency is increased by 30%-50%, the residual oil content in the effluent is reduced to below 10mg/L, the ability to chelate metal ions is strong, the dosage of demulsifier is reduced by 20%-30%, and the environmental friendliness is improved by 30%.

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Abstract

本发明公开了一种基于改性聚醚的破乳剂及其制备方法和应用,属于化工破乳剂技术领域。所述制备方法包括:油酸酯化改性聚醚的制备、多功能协同助剂的合成、破乳剂的复配,本发明应用于工业急冷水破乳,投加量50‑200mg / L,适用10‑60℃、pH3‑11范围。本发明为解决现有破乳剂抗硬水弱、油滴聚并差、兼容性不足的问题,通过助剂引入膦酰胺螯合基团与轻度交联网络,配合改性聚醚界面活性,螯合Ca2+ / Mg2+破除离子桥,促进油滴聚结,高盐硬水中破乳效率超90%,出水残油≤10mg / L;且采用天然腰果酚衍生原料,投加量降低20%‑30%,适配复杂工况。
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