一种改性嵌段硅油及其制备方法、应用

By using a modified block silicone oil preparation method, isopentenyl alcohol polyoxyethylene ether segments are grafted onto the silicone oil backbone to generate a block-structured modified silicone oil, which is used for waterborne acrylate emulsion polymerization. This solves the problem of insufficient antifouling performance of waterborne acrylate coatings and achieves a long-lasting hydrophobic and oleophobic effect.

CN121362331BActive Publication Date: 2026-07-17NANJING VIROSEC CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANJING VIROSEC CO LTD
Filing Date
2025-12-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing waterborne acrylic coatings perform poorly in terms of stain resistance, anti-blocking properties, and water resistance. Furthermore, silicone modification technology suffers from high costs, poor compatibility, and low modification efficiency, making it difficult to achieve a long-lasting dual-repellent antifouling effect.

Method used

Modified block silicone oil is used by covalently grafting multiple isopentenyl alcohol polyoxyethylene ether segments onto the silicone oil backbone to generate a block structure with free radical polymerizable double bonds. This structure is used for waterborne acrylate emulsion polymerization to form a low surface energy layer to achieve hydrophobic and oleophobic effects.

Benefits of technology

It achieves durable hydrophobic, oleophobic, and antifouling properties of waterborne acrylic coatings, reduces the surface energy of the paint film, improves stain resistance and anti-blocking properties, and avoids the environmental risks of organic fluorine.

✦ Generated by Eureka AI based on patent content.

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Abstract

本申请提供了一种改性嵌段硅油及其制备方法、应用,涉及高分子材料技术领域。改性嵌段硅油由端氨基硅油与异戊烯醇聚氧乙烯基醚缩水甘油醚在碱性催化剂存在下进行开环加成反应制成。本发明利用环氧基团与伯胺基团的反应,将多条异戊烯醇聚氧乙烯基醚链段通过醚键共价接枝到硅油主链上,生成一种新型的嵌段结构的有机硅大分子,该大分子同时保留了异戊烯醇末端的可自由基聚合双键,使其能作为大分子单体参与后续的乳液聚合;其分子结构兼具聚醚链段的亲水性与有机硅链段的疏水性。
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