含铜污泥中有价元素的回收方法

By treating copper-containing sludge with Ti-MOFs materials and combining acid leaching, precipitation, and extraction methods, the problem of cross-contamination of metal elements caused by traditional adsorbents was solved, and the efficient recovery and purification of valuable elements in copper-containing sludge was achieved.

CN121362880BActive Publication Date: 2026-07-17QIANSHAN COUNTRY JINRUI COPPER IND CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
QIANSHAN COUNTRY JINRUI COPPER IND CO LTD
Filing Date
2025-09-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional adsorbents are ineffective at adsorbing and separating multiple metal elements in copper-containing sludge, leading to cross-contamination of metal elements. Existing technologies are unable to effectively recover valuable elements.

Method used

The treatment of copper-containing sludge using Ti-MOFs materials includes steps such as dewatering, acid leaching, pretreatment, oxidation, precipitation, and extraction. Through the selective adsorption and modification of Ti-MOFs, combined with precipitation and extraction methods, multi-metal cascade purification is achieved.

Benefits of technology

It improves the recovery rate and purity of various metal elements, solves the problems of competitive adsorption and cross-contamination of metal elements caused by traditional adsorbents, and achieves efficient separation and recovery of multiple metals.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN121362880B_ABST
    Figure CN121362880B_ABST
Patent Text Reader

Abstract

本发明公开了一种含铜污泥中有价元素的回收方法,涉及资源化利用技术领域,回收方法包括:将含铜污泥脱水、烘干、粉碎,得含铜粉末;放入硫酸溶液中酸浸溶解,得到酸浸液;进行预处理和氧化,得含铜溶液;调节至第一pH值,过滤得到第一滤液和氢氧化铁沉淀,加入硫化钠,过滤得到硫化镉沉淀;加入Ti‑MOFs,固液分离,得到第二滤液和滤渣;将滤渣浸入脱附液中,离心分离,得到含铜滤液和Ti‑MOFs;将含铜滤液加入氢氧化钠,过滤,煅烧得到氧化铜;将第二滤液依次加入萃取液、pH调节剂,分别回收锌离子、镍离子和铬离子,本发明能够解决现有技术中传统吸附剂对金属元素进行吸附,会导致多项金属元素竞争吸附,吸附和分离效果差,金属元素交叉污染的技术问题。
Need to check novelty before this filing date? Find Prior Art