稀土微合金化超高强度高韧性热作模具钢及其制备方法

By using rare earth microalloying and catalytic water-gas reaction, the problems of residual oxide film and agglomeration of reinforcing phase in powder metallurgy hot work die steel have been solved, realizing the preparation of die steel with high strength, high toughness and high temperature thermal stability, which is suitable for industrial fields such as aluminum alloy die casting molds, hot extrusion molds and hot forging molds.

CN121402624BActive Publication Date: 2026-07-17XINYU UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-11-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing powder metallurgy hot work die steels suffer from reduced material density and toughness due to residual oxide film on the powder surface forming original particle boundaries. Additionally, conventional external strengthening phases tend to agglomerate in the matrix and have low interfacial bonding strength, resulting in limited high-temperature mechanical properties.

Method used

A rare earth microalloying method is adopted, in-situ reduction is achieved by releasing active hydrogen through the decomposition of rare earth hydrides during the heating process. This is combined with porous amorphous carbon powder with a nickel catalyst to catalyze the water-gas reaction to remove the oxide film, and high-hardness boride is generated by using boron carbide powder to achieve in-situ deep deoxidation and dispersion strengthening.

Benefits of technology

Atomic-level metallurgical bonding between powder particles was achieved, eliminating oxide films and original particle boundaries, resulting in a uniform distribution of low-oxygen-content, defect-free nano-reinforcing phases. This significantly improved the material's impact toughness and high-temperature thermal stability, meeting the requirements for service environments above 600℃.

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Abstract

本发明涉及粉末冶金材料技术领域,公开了稀土微合金化超高强度高韧性热作模具钢及其制备方法,模具钢由4Cr5MoSiV1预合金粉末、稀土氢化物、碳化硼及负载镍催化剂的多孔无定形碳粉制成,制备方法包括混料、包套封装与分级动态反应热脱挥、热等静压致密化及热处理,其中,分级动态反应热脱挥利用稀土氢化物分解产生的活性氢还原粉末表面氧化物,并利用镍催化的碳粉在低温下捕获水蒸气生成CO排出。通过原位化学反应彻底去除粉末表面氧化膜,消除了原始颗粒边界,同时原位生成热稳定性高的纳米强化相,显著提升了模具钢的高温强度、冲击韧性及组织致密度。
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Citation Information

Patent Citations

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  • Rare earth die steel and preparation method thereof

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