一种低膨胀、高容量的硅碳复合负极材料及其制备方法

By preparing silicon-carbon composite materials with a gradient distribution of silicon compounds on a porous carbon support, the problems of volume expansion and insufficient capacity of silicon-carbon composite materials during cycling were solved, achieving the effect of low expansion rate and high capacity.

CN121405065BActive Publication Date: 2026-07-17HUBEI JINGHUAN NEW ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUBEI JINGHUAN NEW ENERGY TECH CO LTD
Filing Date
2025-10-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing silicon-carbon composite anode materials struggle to balance expansion rate control and high capacity. Conventional processes result in poor material stability and rapid capacity decline during cycling.

Method used

By using programmed control of the drying and aging process on a porous carbon support to form a gradient distribution of silicon compounds, combined with heat treatment, a silicon-carbon composite material with elemental silicon inside and silicon oxide and silicon carbide on the surface was prepared.

Benefits of technology

This achievement realizes low expansion rate and high capacity of the material, improves the material's cycle stability and electrochemical performance, and overcomes the contradiction between expansion rate control and high capacity in traditional processes.

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Abstract

本发明属于二次电池负极材料技术领域。更具体地,涉及一种低膨胀、高容量的硅碳复合负极材料及其制备方法。本发明具体制备步骤包括:提供多孔碳载体;配制含硅化合物的溶液作为浸渍液;将所述多孔碳载体浸渍于所述浸渍液中,通过程序化控制干燥或陈化过程,诱导硅化合物在所述多孔碳载体的孔道内,形成梯度分布,得前驱体;在惰性气氛下,对前驱体进行热处理,使含硅化合物热解,以得到所述硅碳复合负极材料。在所述梯度分布中,位于材料颗粒内部的硅元素至少部分呈单质硅的形式存在;位于材料颗粒表面的硅元素至少部分以硅氧化物和 / 或硅碳化物的形式存在。
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