一种抗氧化改性碳石墨材料及其制备方法

By combining medium-temperature pitch, modified silica sol, and core-shell particles, a dense glassy carbon structure and an aluminosilicate ceramic phase are formed, which solves the problem of poor oxidation resistance of artificial graphite at high temperatures and improves the high-temperature stability and mechanical properties of the material.

CN121493964BActive Publication Date: 2026-07-17INNER MONGOLIA PLANETARY NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INNER MONGOLIA PLANETARY NEW MATERIAL TECH CO LTD
Filing Date
2025-12-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Artificial graphite has poor oxidation resistance in high-temperature and oxygen-rich environments. In existing technologies, the viscosity of nano-silica coatings decreases at high temperatures and the material's plastic deformation capacity is insufficient, leading to easy cracking.

Method used

A combination of medium-temperature asphalt, modified silica sol, and artificial graphite powder is used. Through heat treatment and molding, a dense glassy carbon structure is formed by combining the catalytic effect of aluminum dihydrogen phosphate and boric acid aqueous solution. Core-shell particles are added to enhance the material's oxidation resistance and mechanical properties.

Benefits of technology

It improves the oxidation resistance and mechanical properties of carbon graphite materials, and enhances the material's resistance to crack propagation and high-temperature stability.

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Abstract

本发明涉及改性碳石墨材料技术领域,具体公开了一种抗氧化改性碳石墨材料及其制备方法,包括以下重量份原料:30‑34份中温沥青、4‑6份改性硅溶胶和10‑12份人造石墨粉;本发明从两方面入手,一是加入了磷酸二氢铝和硼酸水溶液,磷酸二氢铝会促使沥青在炭化时形成更致密、更坚固的玻璃炭结构,磷酸二氢铝分解产生的五氧化二磷能与硼酸脱水生成的氧化硼生成具有抗氧化作用的玻璃相;二是加入了核壳粒子,核壳结构的壳层为九水合硝酸铝水解生成的氢氧化铝结构,内核为环氧化纳米碳化硅;通过两者的协同作用,提高了碳石墨材料的力学性能和抗氧化性能。
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