从废水中选择性回收磷的填充床双极膜电渗析系统及方法

By constructing a packed-bed bipolar membrane electrodialysis system and adopting a multi-stage series continuous operation method, the selective separation of chloride ions and phosphate ions in anaerobic digestion liquid was achieved using a mixed resin bed. This solved the problems of insufficient phosphoric acid purity and unstable operation in existing technologies, and realized efficient phosphoric acid resource recovery and stable treatment.

CN121494154BActive Publication Date: 2026-07-17TIANJIN POLYTECHNIC UNIV +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TIANJIN POLYTECHNIC UNIV
Filing Date
2026-01-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are unable to effectively separate chloride ions and phosphate ions in anaerobic digestion liquids, resulting in insufficient purity of phosphoric acid products and unstable operation, making continuous processing difficult.

Method used

A packed-bed bipolar membrane electrodialysis system with both chloride and phosphorus separation capabilities was constructed. Through a multi-stage series continuous operation system, a packed-bed bipolar membrane electrodialysis device was used to achieve selective separation and efficient recovery of chloride ions and phosphate ions by utilizing a mixed resin bed of anion and cation exchange resins.

Benefits of technology

It achieves high-purity recovery of phosphorus resources, reduces chloride ion content, improves system operational stability, and enables simultaneous and efficient removal of nitrogen, phosphorus, and potassium nutrients from wastewater, reducing the burden on the aquatic ecological environment.

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Abstract

本发明公开了一种从废水中选择性回收磷的填充床双极膜电渗析系统及方法,属于污水处理及资源回收技术领域。本发明解决了现有从废水中回收磷时存在氯磷分离效率低、回收率不足、难以连续运行的问题,通过构建具有氯 / 磷选择分离与营养盐高效脱除功能的填充床双极膜电渗析系统,并开发多级串联连续运行工艺,可有效抑制酸室中氯离子与磷酸根同步富集,从而显著提高磷回收液的纯度;同时还能实现氮、磷、钾的协同高效脱除与回收,大幅降低厌氧消化液对水体环境的营养盐污染负荷,在废水处理与资源回收领域具有良好的应用前景。
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