一种井下消焰与定向结晶强化的防火涂料及其制备方法

By introducing LBL-modified ZIF-67, mullite powder, and hollow alumina spheres into the underground fire retardant coating, an interlocking structure of flame extinguishing core and directional crystalline phase is formed, solving the problems of easy loosening and insufficient flame extinguishing capacity of existing coatings at high temperatures, and achieving efficient flame extinguishing and structural strengthening effects.

CN121495415BActive Publication Date: 2026-07-17CHINA UNIV OF MINING & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA UNIV OF MINING & TECH
Filing Date
2025-12-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing underground fireproof coatings lack active flame-extinguishing components, cannot effectively adsorb combustible media such as methane and coal dust underground, and the coating is prone to loosening at high temperatures, making secondary reinforcement and repair impossible, resulting in interruption of protection.

Method used

Using water-based acrylic emulsion as the film-forming base material, LBL-modified ZIF-67 as the flame-retardant core, and mullite powder and hollow alumina spheres as oriented crystalline phases, a coating with active adsorption flame retardancy and oriented structural reinforcement is formed through synergistic compatibility. Combined with LBL interlayer assembly technology and a dense columnar crystal layer induced by silica sol, efficient film formation and high-temperature stability are achieved.

Benefits of technology

It achieves efficient film formation and adhesion, active adsorption and flame extinguishing, and directional structural reinforcement. The coating maintains high integrity at high temperatures, has a fast flame extinguishing response, and a low coating peeling rate, which can effectively suppress the rapid spread of flames.

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Abstract

本发明公开了一种井下消焰与定向结晶强化的防火涂料及其制备方法,属于涂料组合物技术领域,包括以下原料:水性丙烯酸乳液、LBL改性ZIF‑67、莫来石粉、空心氧化铝球、硅溶胶、乙二醇乙醚醋酸酯、聚羧酸钠盐分散剂、聚醚改有机硅类消泡剂、去离子水。本发明采用上述的一种井下消焰与定向结晶强化的防火涂料及其制备方法,以水性丙烯酸乳液为成膜基料、LBL改性ZIF‑67为消焰核心、莫来石粉+空心氧化铝球为定向结晶相,通过各组分的协同兼容,同步实现高效成膜附着‑主动吸附消焰‑定向结构强化功能,协同发挥水性乳液的成膜性、改性ZIF‑67的甲烷吸附与消焰性、结晶相的机械与高温稳定性。
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