一种高附着力丙烯酸涂料及其制备方法

By introducing epoxy-modified monomers with sophisticated molecular structures into acrylic coatings, and combining flexible crown ether rings with rigid epoxy skeletons, the problems of insufficient adhesion and brittleness of coatings on non-polar substrates are solved, achieving a balance between high adhesion and toughness, and improving the protective performance of the coating.

CN121555020BActive Publication Date: 2026-07-17NANXIONG YALTON CHEM CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANXIONG YALTON CHEM CO LTD
Filing Date
2025-11-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Acrylic coatings have insufficient adhesion on non-polar or low surface energy substrates. Existing modification methods lead to increased coating brittleness, making it difficult to balance adhesion and toughness.

Method used

By using epoxy-modified monomers with sophisticated molecular structures, flexible crown ether rings are chemically synthesized and incorporated into a rigid epoxy framework to form a dynamic interfacial bonding mechanism. The crown ether rings are used as molecular-level dampers to absorb mechanical energy and improve interfacial stress dissipation.

Benefits of technology

When subjected to external impact or scratches, the coating maintains complete adhesion, preventing the formation of microcracks and improving long-term protective performance and reliability in harsh environments.

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Abstract

本发明涉及一种高附着力丙烯酸涂料及其制备方法,属于涂料技术领域。核心在于设计并合成了一种新型环氧改性单体,该单体通过将冠醚结构原位引入环氧基团,成功应用于丙烯酸乳液的共聚改性,所制备的改性丙烯酸乳液与助剂配制成涂料后,不仅通过环氧基团显著提升了涂料的初始附着力,更通过冠醚结构的“原位增韧”效应,在外力冲击时能有效吸收应力,防止涂层脆性脱落。测试表明,本发明涂料在保持高硬度与良好柔韧性的同时,其冲击后和刮擦后的附着力保持率远优于传统环氧改性涂料,实现了附着力与韧性的协同提升,具有显著的应用价值。
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