一种水性聚氨酯防火涂料的制备方法

By using dihydroxymethylimidazolium DOPO as a chain extender, a waterborne polyurethane fire-retardant coating was prepared, solving the problems of water resistance and flame retardancy of polyurethane coatings and achieving environmentally friendly and highly efficient fire-retardant performance.

CN121555065BActive Publication Date: 2026-07-17NANTONG BAOLILAI COATINGS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANTONG BAOLILAI COATINGS CO LTD
Filing Date
2025-07-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyurethane coatings suffer from high solvent volatility, serious pollution, and significant health hazards. Water-based polyurethane coatings also have poor water resistance and are flammable, limiting their application in the fire protection field.

Method used

Waterborne polyurethane fire-retardant coatings were prepared by reacting dihydroxymethylimidazolium (DOPO) with polyester polyol and diisocyanate as a chain extender. The water resistance and flame retardant properties of the coatings were improved by the flame retardancy and aromatic ring structure of DOPO.

Benefits of technology

The prepared waterborne polyurethane fire-retardant coating exhibits good emulsion stability, significantly reduces water absorption and heat release rate during combustion, and enhances the coating's water resistance and flame retardant properties.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及涂料技术领域,且公开了一种水性聚氨酯防火涂料的制备方法,二羟甲基咪唑DOPO,其含有的二羧基和二羟基基团,可以作为聚氨酯的水性扩链剂,与聚酯多元醇和二异氰酸酯进行聚合反应,得到水性聚氨酯防火涂料。在长时间放置下乳液不分层,无沉淀,具有良好的乳液稳定性。并且二羟甲基咪唑DOPO含有耐水性的芳环结构,有利于降低聚氨酯漆膜的吸水率,提高耐水性能。二羟甲基咪唑DOPO形成氮磷协效阻燃体系,并键合到聚氨酯分子链中,对聚氨酯漆膜起到很好的本质阻燃效果,显著降低了聚氨酯燃烧时的热释放速率峰值和总热释放量,增强了聚氨酯的阻燃性能。
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