一种缓释型电子受体 / 导电介体核壳微球及其制备方法与在餐厨垃圾厌氧消化中的应用

By utilizing slow-release electron acceptor/conductive mediator core-shell microspheres in the anaerobic digestion of food waste, the synergistic effect of slow-release nitrates in the core layer and conductive materials in the shell layer has solved the H2S pollution problem, increased methane yield, and achieved resource recycling.

CN121607097BActive Publication Date: 2026-07-17QINGDAO UNIV OF TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
QINGDAO UNIV OF TECH
Filing Date
2025-12-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are ineffective in suppressing hydrogen sulfide (H2S) pollution during the anaerobic digestion of food waste. Furthermore, conventional methods suffer from high costs, significant impact on methane yield, high safety risks, and insufficient resource utilization.

Method used

The system employs slow-release electron acceptor/conductive mediator core-shell microspheres. The core layer consists of nitrates embedded in a polymer, while the shell layer is composed of modified hydrothermal carbon powder and magnetic nano-zero-valent iron. Through synergistic effects, it achieves hydrogen sulfide inhibition, methane production enhancement, and resource recycling.

Benefits of technology

It achieves efficient in-situ control of H2S, keeping the H2S concentration in the gas phase stable below 50ppm, increasing methane yield by 15%-20%, reducing operation and maintenance costs, and the material is biodegradable with no secondary pollution.

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Abstract

本发明涉及固体废弃物资源化利用及环境工程技术领域,尤其涉及一种缓释型电子受体 / 导电介体核壳微球及其制备方法与在餐厨垃圾厌氧消化中的应用。本发明通过核壳微球的核层与壳层协同作用,构建了“源头抑制‑原位固定‑增效产甲烷”的三重作用机制,实现了H2S的高效原位阻控,同时显著提升了甲烷产率。核层的缓释结构与可生物降解骨架确保硝酸盐在整个厌氧消化周期内持续稳定释放,避免了传统方法需要频繁投加的弊端;壳层材料采用餐厨垃圾沼渣制备的改性水热炭,实现了“以废治废”的资源循环利用;同时,核层采用可生物降解聚合物,整个微球在消化结束后可随沼渣一同资源化利用,无二次污染风险。
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