一种用于采掘的耐腐蚀抗冲击硬质合金及其制备方法

By using a gradient structure of WC cemented carbide and combining composite binder phases and additives, the corrosion problem of traditional WC-Co alloys in harsh environments has been solved, thereby improving the alloy's corrosion resistance, wear resistance, and thermal stability, and extending its service life.

CN121629208BActive Publication Date: 2026-07-17ZIGONG CEMENTED CARBIDE CORP +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZIGONG CEMENTED CARBIDE CORP
Filing Date
2025-12-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional WC-Co cemented carbide corrodes severely in acidic mining environments with abundant water, high chloride ion content, or low pH, leading to a decline in alloy performance and making it unable to meet the comprehensive performance requirements of mining tools in complex and harsh environments.

Method used

WC cemented carbide with a gradient structure improves the corrosion resistance, wear resistance and thermal stability of the alloy by replacing the traditional Co binder phase with a gradient sintering process using specific composite binder phases and additives (Sc2O3, TiB2, AlN).

Benefits of technology

It significantly improves the overall performance of the alloy in harsh environments, extends its service life, achieves a balance between hardness and toughness, and enhances wear resistance and thermal stability.

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Abstract

一种用于采掘的耐腐蚀抗冲击WC硬质合金的制备方法,属于金属粉末加工领域技术领域,是以WC粉、粘结相复合粉和添加剂复合制备表层分散粉体,里层分散粉体和最里层分散粉体,按顺序分层压制形成复合生坯,然后进行梯度烧结获得梯度WC硬质合金,所述添加剂由Sc2O3粉、TiB2粉和AlN粉组成,粘结相复合粉由Ni粉、Cu粉和ZrH2预合金化制得。本发明中通过梯度变化的Ni‑Cu‑Zr粘结相梯度添加,并梯度加入Sc2O3、TiB2、AlN,结合梯度煅烧制备的WC合金具有效实现了硬度‑韧性平衡,具有优异的硬度和强韧性,同时耐蚀性和耐磨损性能得到显著提高,在富水、富含氯离子等苛刻环境中依然具有优异的性能。
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