多元稀土氧化物复合型催化剂及其制备方法和应用

By forming a La2O3 and Nd-O solid solution under high temperature and pressure and then performing stepwise calcination, a multi-element rare earth oxide composite catalyst was prepared, which solved the problems of scarce precious metal catalyst resources and insufficient uniformity of rare earth oxide composite catalysts, and achieved a highly efficient purification effect for automobile exhaust.

CN121648903BActive Publication Date: 2026-07-17HEBEI UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HEBEI UNIV OF TECH
Filing Date
2025-12-11
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing precious metal catalysts for automobile exhaust purification suffer from resource scarcity and high cost, while rare earth oxide composite catalysts have shortcomings in terms of nanoscale uniformity and composite system uniformity, which affect catalytic performance.

Method used

By carrying out solid-phase reaction under high temperature and high pressure oxygen partial pressure environment, a La2O3 and Nd-O solid solution is formed, the valence state distribution of Nd element is regulated, and a spherical micromorphology is formed through a step-by-step calcination process to prepare a multi-element rare earth oxide composite catalyst, which is suitable for exhaust gas treatment of different vehicle models.

Benefits of technology

It improves the catalyst's reactivity and specific surface area, reduces the amount of precious metals used, and achieves efficient purification of exhaust gases from different vehicle models, adapting to the catalytic requirements of various vehicle types.

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Abstract

本发明为一种多元稀土氧化物复合型催化剂及其制备方法和应用。该催化剂的组成包括:载体及其负载其上的三元复合材料;载体与三元复合材料的质量比例为4:6~7:3;其中,载体为γ‑Al2O3;三元复合材料由La2O3相和Nd‑O固溶体相构成,La2O3相占比20%‑40%,Nd‑O固溶体相占比60%‑80%;Nd‑O固溶体相中Nd元素为Nd3+ / Nd4+两种价态,两种价态摩尔比例为:Nd3+占比35%‑70%,Nd4+占比30%‑65%。本发明得到的催化剂通过调整La / Nd比例和Nd价态分布实现优化催化剂的储氧能力和热稳定性,适配多种车辆催化要求。
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