一种等离子喷涂用高纯度球形钨基复合粉末

By preparing high-purity spherical tungsten-based composite powder, the problems of single composition, poor morphological adaptability and low interfacial bonding strength of tungsten powder for plasma spraying are solved, achieving efficient coating corrosion resistance and long-life tungsten cathode protection, which is suitable for the rare earth electrolysis industry.

CN121649382BActive Publication Date: 2026-07-17BAOTOU PREMIER NEW MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BAOTOU PREMIER NEW MATERIALS CO LTD
Filing Date
2025-12-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing tungsten powders for plasma spraying suffer from problems such as limited composition design, poor morphology and process compatibility, low interfacial bonding strength, and uneven distribution of rare earth modification, resulting in short coating service life and making it difficult to meet the long-term use requirements of the rare earth electrolysis industry.

Method used

A method for preparing high-purity spherical tungsten-based composite powder is adopted. Through rare earth-modified zirconium oxide nano-processing, precision atomization and composite of tungsten-based composite powder, and vacuum annealing treatment, a dual protection system is formed with an internal dispersed corrosion-resistant phase and a dense surface shell. Combined with glucose carbon template and citric acid chelation technology, the high purity, sphericity and corrosion resistance of the finished powder are ensured.

Benefits of technology

It significantly improves the corrosion resistance and bonding strength of the coating under high temperature conditions, reduces the corrosion rate, extends the service life of the tungsten cathode, and optimizes the particle size distribution and flowability, making it suitable for plasma spraying processes.

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Abstract

本发明公开了一种等离子喷涂用高纯度球形钨基复合粉末,属于金属复合材料技术领域。所述复合粉末通过溶胶‑凝胶‑碳模板法制备纳米多孔稀土改性氧化锆耐蚀相,经预合金化配合二次雾化工艺形成核‑壳‑内部弥散结构,再经真空退火优化;复合粉末以钨为核,表面含5‑20nmWOx / 稀土氧化物过渡层,粒度15‑45μm,球形度≥0.95。本发明针对现有钨粉成分单一、球形度低、耐熔盐腐蚀差、界面结合弱的缺陷,通过双重耐蚀防护与界面调控,显著提升涂层耐蚀性与结合强度,使稀土熔盐电解钨阴极服役寿命延长50%以上,完美适配等离子喷涂工艺。
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