蓝色方解石发光光谱精确表征与定量分析方法

By combining multi-wavelength excitation and time-resolved spectral analysis with luminescence center identification algorithms and spectral deconvolution techniques, the problem of accurately characterizing the luminescence properties of blue calcite has been solved, achieving highly sensitive and accurate quantitative analysis suitable for scientific research and gemological applications.

CN121656201BActive Publication Date: 2026-07-17CHINA UNIV OF GEOSCIENCES (BEIJING)

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA UNIV OF GEOSCIENCES (BEIJING)
Filing Date
2025-12-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing mineral luminescence analysis methods cannot accurately characterize the luminescence properties of blue calcite, and it is difficult to effectively distinguish and quantify the contributions of different luminescence centers, resulting in low sensitivity and poor accuracy, which cannot meet the high-precision analysis needs of scientific research and application fields.

Method used

By combining multi-wavelength excitation with time-resolved spectral analysis, along with luminescence center identification algorithms and spectral deconvolution analysis techniques, and through various excitation wavelengths and temperature gradient tests, we can identify and distinguish manganese ions, rare earth ions, and lattice defect luminescence centers in blue calcite, and establish a quantitative relationship between luminescence intensity and content.

Benefits of technology

It achieves comprehensive characterization and high-precision quantitative analysis of the luminescence properties of blue calcite, with an identification accuracy of 98%, a quantitative detection sensitivity improved by 2-3 orders of magnitude, and a quantitative accuracy of over 95%, providing comprehensive and reliable support for mineral identification and gemological applications.

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Abstract

本发明属于矿物光谱分析技术领域,提供蓝色方解石发光光谱精确表征与定量分析方法。方法采用265nm、335nm和405nm三种激发波长结合80K‑320K温度梯度测试和时间分辨光谱技术,通过发光中心识别算法精确区分锰离子、稀土离子和缺陷发光中心,采用光谱解卷积技术实现发光峰的精确分离和量化,建立基于参比的定量分析框架,检测灵敏度达,定量准确度>95%,为蓝色方解石的科学研究和应用提供重要技术支持。
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