一种催化剂、制备方法与在甲醇氧化合成甲醛中的应用

The iron molybdate nanosphere catalyst prepared by the reverse microemulsion method solves the problems of low active site utilization and insufficient stability of traditional iron-molybdenum catalysts in the methanol oxidation to formaldehyde process, and achieves catalytic performance with high activity, high selectivity and long life.

CN121669251BActive Publication Date: 2026-07-17JINAN ENLIGHTEN BIOTECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JINAN ENLIGHTEN BIOTECH CO LTD
Filing Date
2025-12-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional iron-molybdenum catalysts have problems such as low utilization of active sites, insufficient structural stability, and easy occurrence of deep oxidation side reactions in the process of methanol oxidation to formaldehyde. In particular, the active component molybdenum is easily lost at high temperatures, which leads to a shortened catalyst life.

Method used

The catalyst was prepared by the reverse microemulsion method. The reverse microemulsion system was formed by mixing surfactant, co-surfactant and oil phase. The dropwise addition process of iron salt and molybdenum salt mixture was controlled to form iron molybdate nanosphere aggregate catalyst. After calcination, a porous structure was formed, thus optimizing the microstructure of the catalyst.

Benefits of technology

It significantly improved the activity and stability of the catalyst, suppressed deep oxidation side reactions, extended the catalyst's lifespan, and achieved a highly selective and high-conversion methanol-to-formaldehyde oxidation reaction.

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Abstract

本发明公开了一种催化剂、制备方法与在甲醇氧化合成甲醛中的应用,属于甲醛合成技术领域。在室温下,表面活性剂、助表面活性剂和油相混合,得到反相微乳液体系;铁盐水溶液与反相微乳液体系混合,得到混合液;混合液滴加至钼盐水溶液中,得到前驱体,干燥、焙烧,得到催化剂。所得催化剂具有极高的比表面积和均匀分散的活性位点,有效提升了催化本征活性;其内部形成的丰富多级孔道结构,极大地优化了反应物与产物的传质扩散,从而显著抑制了深度氧化等副反应,提高了反应选择性;该方法所构建的稳固纳米结构及良好的结晶性,有效抑制了活性组分在反应过程中的烧结和流失,大幅增强了催化剂的稳定性。
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Citation Information

Patent Citations

  • Iron-molybdenum-based catalyst for preparing formaldehyde through methanol oxidation and preparation method of iron-molybdenum-based catalyst

    CN114345362A