一种基于双重动态网络结构的高效界面自修复碳纤维双马来酰亚胺复合材料及其制备方法

By constructing a dual dynamic network structure at the interface of carbon fiber and bismaleimide composite materials, and utilizing the reversibility of hydrogen bonds and Diels-Alder bonds, the problem of low repair efficiency in traditional self-healing systems is solved, achieving efficient and repeated interface self-healing effects, which are suitable for aerospace and high-end equipment fields.

CN121673830BActive Publication Date: 2026-07-17NANCHANG HANGKONG UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANCHANG HANGKONG UNIVERSITY
Filing Date
2026-01-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional self-healing systems that rely on Diels-Alder bonds have low repair efficiency in highly cross-linked rigid thermosetting resin networks, making it difficult to meet the high-efficiency and rapid self-healing performance requirements of high-end equipment and other fields, and interface microcracks are difficult to repair effectively.

Method used

By constructing a dual dynamic network structure at the interface of carbon fiber and bismaleimide composite material, and utilizing the reversibility of hydrogen bonds and Diels-Alder bonds, efficient self-repair of interfacial microcracks is achieved, including steps such as surface oxidation treatment, hyperbranched polyester grafting, and curing treatment.

Benefits of technology

It achieves efficient and repeated self-healing of composite material interfaces, with an initial repair efficiency of up to 96.4% and a repair efficiency of 90.3% after multiple repairs. It has a fast repair speed and low cost, and is suitable for the long-term service requirements of aerospace and high-end equipment.

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Abstract

本发明公开了一种基于双重动态网络结构的高效界面自修复碳纤维双马来酰亚胺复合材料及其制备方法,属于复合材料技术领域。方法包括:通过碳纤维表面氧化、含Diels‑Alder键超支化聚酯接枝,再与双马来酰亚胺树脂和二烯丙基双酚A混合固化,在界面构建基于氢键与Diels‑Alder键的双重动态网络结构。该复合材料初始界面修复效率达96.4%,多次修复后仍达90.3%,修复条件温和,工艺简单易工业化,适用于航空航天、高端装备领域。
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