一种具有两亲性协同效果的海洋防腐防污涂料、制备方法及应用

By co-polymerizing fluorinated low surface energy and zwitterionic polymerizable monomers with methyl vinyl MQ type silicone resin in marine protective coatings, and combining them with a zinc powder conductive network, the problems of interface failure and performance degradation in anti-corrosion and antifouling coatings are solved, achieving stable anti-corrosion and antifouling effects.

CN121673900BActive Publication Date: 2026-07-17CHANGSHU INSTITUTE OF TECHNOLOGY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHANGSHU INSTITUTE OF TECHNOLOGY
Filing Date
2026-01-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing marine protective coatings cannot achieve both corrosion and fouling protection without increasing construction complexity and maintenance costs, and the coatings are prone to performance degradation due to interface failure and ion migration.

Method used

An amphiphilic synergistic film-forming network was constructed by copolymerizing fluorine-containing low surface energy polymerizable monomers, zwitterionic polymerizable monomers, and methyl vinyl MQ type silicone resin. Zinc powder was introduced into the coating to construct a conductive network, forming a stable cross-linked curing structure.

Benefits of technology

A synergistic effect of antifouling adhesion and cathodic protection is achieved in a single coating, reducing the probability of biofilm formation, improving the coating's durability and corrosion resistance, and reducing interface failure and localized corrosion.

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Abstract

本发明公开了一种具有两亲性协同效果的海洋防腐防污涂料,包括A组分和B组分,A组分按重量份数计包括:两亲性协同成膜物预聚物树脂 30~120份、锌粉 100~350份、导电助剂 0.1~10份、触变防沉剂 0.2~15份、助剂 0.2~10份、第一溶剂 20~300份;B组分按重量份数计包括:热引发剂偶氮二异丁腈 0.2~8份、交联剂 0.2~15份、可聚稀释单体 2~80份、第二溶剂 2~150份;两亲性协同成膜物预聚物树脂是含氟低表面能可聚单体、含羧基两性离子可聚单体、甲基乙烯基MQ型硅树脂通过自由基共聚合反应合成的可溶性预聚物。本发明还公开了其制备方法以及应用,通过A组分20~60份和B组分2~20份混合涂覆固化成涂层。本发明同时实现稳定的防腐及防污性能。
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