高粘结性隔膜无氟涂布液及其制备方法与应用

Modified acrylic emulsion prepared by copolymerization reaction is used for bonding lithium battery separators and electrodes, which solves the problems of toxic solvents and poor flexibility of PVDF binders. It realizes a fluorine-free aqueous coating liquid with high bonding strength and flexibility, and improves the safety and life of lithium batteries.

CN121673991BActive Publication Date: 2026-07-17JIESHOU CITY TIANHONG PACKAGING MATERIAL

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIESHOU CITY TIANHONG PACKAGING MATERIAL
Filing Date
2026-02-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In current lithium battery manufacturing, polyvinylidene fluoride (PVDF) binders use the toxic solvent N-methylpyrrolidone (NMP), which has poor flexibility and makes it difficult to improve the bonding strength and flexibility between the separator and the electrode.

Method used

A modified acrylic emulsion was prepared by copolymerization of hydroxy acrylate monomers, N-vinylcaprolactam and 1,1,3,3-tetramethyl-1,3-divinyldisilazane, and an antifoaming agent was added to prepare a fluorine-free aqueous coating solution for bonding the diaphragm and the electrode.

Benefits of technology

It improves the bonding strength between the separator and the electrode, enhances the flexibility of the separator, improves the safety and cycle life of lithium batteries, and reduces cost and environmental risks.

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Abstract

本发明公开了一种高粘结性隔膜无氟涂布液及其制备方法与应用,涉及粘结剂技术领域,本发明先通过共聚反应制备改性丙烯酸乳液,再由该改性丙烯酸乳液制备涂布液;本发明制备的涂布液既属于无氟粘结剂也属于水性粘结剂,相对于本领域常用的粘结剂PVDF来说,环保性与安全性更高,成本也更低,并且能够有效提高隔膜与极片之间的粘结强度,同时还能改善隔膜的柔韧性,从而提升锂电池的循环寿命,增强锂电池的安全性。
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