一种扩散渗析膜的制备方法

By introducing bifunctional functional group compounds and tertiary amines for modification during the preparation of diffusion dialysis membranes, the crosslinking structure and charge properties are optimized, solving the problem of balancing H+ dialysis coefficient and separation factor, and achieving efficient acid recovery.

CN121715056BActive Publication Date: 2026-07-17XIAN JINGZHI NEW MATERIAL TECHNOLOGY CO LTD
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Patent Information

Application Number
CN202512006156.1
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2025-12-29
Publication Date
2026-07-17
Estimated Expiration
2045-12-29

AI Technical Summary

Technical Problem

Existing diffusion dialysis membranes have difficulty simultaneously achieving both H+ dialysis coefficient and separation factor, especially in terms of separation factor, which limits the improvement of acid recovery efficiency and purity.

Method used

By introducing bifunctional functional compounds into the preparation process to crosslink with chloromethylated polysulfone and modifying it with tertiary amine solution, and controlling the reaction temperature and time, the crosslinking structure and charge properties are optimized, thereby achieving synergistic regulation of H+ permeability coefficient and separation factor.

Benefits of technology

A diffusion dialysis membrane with both high separation factor and high H+ dialysis coefficient was prepared, which improved the efficiency and purity of acid recovery.

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Abstract

本发明提供一种扩散渗析膜的制备方法,包括以下步骤:S1:将一定量的双功能官能团化合物加入氯甲基化聚砜溶液中,加入完毕后首先在低温下进行反应,之后升高温度继续反应得到铸膜液,将所得铸膜液用刮刀涂在基板上,热烘干后得到交联基膜;S2:将S1中得到的交联基膜浸渍在叔胺溶液中反应一段时间后即得扩散渗析膜。本发明以氯甲基化聚砜为原料,通过双功能官能团化合物进行交联改性,采用溶液浇铸法制备交联膜,最后通过叔胺溶液对交联膜进行荷电化处理。本发明制备的扩散渗析膜制备方法简单,选择分离性能显著,有利于工业化应用。
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Citation Information

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