高粘附性、高透明液晶聚酰亚胺薄膜及制备方法

By inducing the vertical orientation of mesocrystalline units and the orientation of polar groups using a spatial electric field, the problems of transparency, expansion, and adhesion of polyimide films were solved, and a highly adhesive liquid crystal polyimide film with excellent optical properties and mechanical reliability was prepared, which is suitable for flexible electronic devices.

CN121718048BActive Publication Date: 2026-07-17JIANGHAN UNIVERSITY +2
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGHAN UNIVERSITY
Filing Date
2026-02-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyimide films cannot simultaneously achieve high transparency, low coefficient of thermal expansion, and high interfacial adhesion, which makes them prone to delamination and peeling in flexible electronic devices, affecting the long-term reliability of the devices.

Method used

By inducing the vertical orientation of mesocrystalline units through a spatial electric field, and combining the migration and orientation of polar groups towards the substrate interface, electrostatic interactions and interfacial chemical bonding are enhanced, thus preparing highly adhesive and highly transparent liquid crystal polyimide films.

Benefits of technology

This achieves a combination of high transparency and low coefficient of thermal expansion, significantly improving the interfacial adhesion and mechanical reliability of the film, meeting the stringent requirements of high-end flexible electronic devices.

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Abstract

本发明公开了一种高粘附性、高透明液晶聚酰亚胺薄膜及制备方法。方法通过利用空间电场诱导介晶基元垂直取向以获取高透明性和低热膨胀系数的同时,同步驱动前驱体分子中的极性基团向基板界面迁移与定向,通过增强静电相互作用与界面化学键合,显著提升了薄膜的界面粘附性,制得的薄膜兼具优异的光学性能、热稳定性和机械可靠性,工艺简单、绿色高效。本发明制备的聚酰亚胺薄膜在保持优异耐热性和机械强度的同时,实现了高透明度和高剥离强度的完美结合,满足高端柔性电子器件的严苛要求,在柔性电子与显示领域具有广阔应用前景。
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Citation Information

Patent Citations

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