基于催化剂的对位酯快速合成工艺

By combining a deep eutectic solvent with a metal catalyst, a low-temperature homogeneous reaction environment was constructed, which solved the problems of high energy consumption and product quality in the synthesis of polyethylene terephthalate at high temperatures. This enabled efficient and low-energy esterification and polycondensation reactions, improving the overall performance of polyester products.

CN121736246BActive Publication Date: 2026-07-17LIAONING JINGLI IND CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
LIAONING JINGLI IND CO LTD
Filing Date
2025-12-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyethylene terephthalate (PET) synthesis processes require high temperatures, resulting in high energy consumption, long reaction times, and high temperatures can easily lead to an increase in diethylene glycol byproducts and polymer thermal degradation and yellowing.

Method used

A deep eutectic solvent system of choline chloride and diol was formed, and a metal catalyst was used to construct a low-temperature homogeneous reaction environment. Homogeneous polymerization of terephthalic acid was achieved through gradient concentration control and synergistic catalysis.

Benefits of technology

It significantly reduces reaction energy consumption, shortens reaction cycle, improves product quality, reduces diethylene glycol byproducts and polymer thermal degradation, and enhances reaction efficiency and product appearance quality.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN121736246B_ABST
    Figure CN121736246B_ABST
Patent Text Reader

Abstract

本发明涉及高分子材料合成技术领域,公开了基于催化剂的对位酯快速合成工艺,该工艺包括以下步骤:将氯化胆碱、金属催化剂与部分二元醇组分混合加热,原位形成深共熔溶剂催化介质;向该介质中加入对苯二甲酸,在低温下搅拌使其完全溶解,形成均相反应混合物;随后升温进行酯化反应,并在反应过程中梯度滴加剩余的二元醇组分;最后在较低的温度下减压进行缩聚反应。本发明通过构建低温均相反应体系,消除了固‑液传质瓶颈,显著提升了反应速率,缩短了反应周期;同时,温和的反应条件有效抑制了副反应的发生和聚合物的热降解,使得最终产品具有二甘醇含量低、色相好等优点。
Need to check novelty before this filing date? Find Prior Art