丙烯酸类改性TPU树脂及其制备方法与在低温固化油墨中的应用

By modifying TPU resin with acrylic resin and combining low-temperature crosslinking and multiple crosslinking networks, the problems of high-temperature curing and compatibility of TPU resin in inks are solved, achieving high-performance low-temperature curing and excellent adhesion and durability, suitable for a variety of substrates.

CN121758720BActive Publication Date: 2026-07-17SHANDONG INOV POLYURETHANE

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG INOV POLYURETHANE
Filing Date
2026-03-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing thermoplastic polyurethane (TPU) resins have problems in ink applications, such as high curing temperature, insufficient adhesion to low surface energy substrates, and poor chemical and weather resistance. Traditional physical blending systems lead to compatibility issues and uneven crosslinking.

Method used

TPU resin was modified with acrylic resin. Acrylic segments were grafted onto the TPU main chain, and multiple crosslinking was carried out by combining aliphatic blocked isocyanate and oxazoline polymer. Low-temperature curing was performed using a twin-screw extruder, and the amount of catalyst and reaction conditions were controlled to form a dense crosslinked network.

Benefits of technology

It achieves low-temperature curing performance, improves adhesion, flexibility and toughness, broadens the application range of inks on heat-sensitive substrates, and ensures the coating's resistance to yellowing and scratching.

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Abstract

本发明属于聚氨酯弹性体及其应用技术领域,具体涉及丙烯酸类改性TPU树脂及其制备方法与在低温固化油墨中的应用。本发明所述的丙烯酸类改性TPU树脂,包括以下原料:多元醇、羟基和羧基丙烯酸类树脂、二异氰酸酯、扩链剂、催化剂。将丙烯酸类改性TPU树脂用于制备低温固化油墨,主要步骤为:将丙烯酸类改性TPU树脂溶于溶剂中,依次加入肪族封闭型多异氰酸酯、恶唑啉类聚合物等搅拌熟化,得到低温固化油墨;所述脂肪族封闭型多异氰酸酯为HDI三聚体。本发明的丙烯酸树脂化学改性的TPU树脂及其制备方法,显著提高TPU树脂与丙烯酸树脂的相容性,具有低温固化性能、附着力、柔韧性及耐性,适用于高性能低温固化油墨领域。
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