一种多级协同强化的纳米共价连接石墨烯预制体及其在金属基复合材料中的应用

The method for preparing nano-covalently linked graphene preforms through multi-level synergistic reinforcement solves the problems of insufficient compressive strength and incomplete infiltration of graphene in metal matrix composites, improves conductivity and mechanical properties, and reduces production costs.

CN121778718BActive Publication Date: 2026-07-17UNIV OF SCI & TECH OF CHINA
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
UNIV OF SCI & TECH OF CHINA
Filing Date
2025-12-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, graphene in metal matrix composites suffers from problems such as insufficient compressive strength of the physical overlap structure, graphene lattice defects caused by high-temperature deposition, and nanostructure collapse during metal infiltration.

Method used

A multi-level synergistic reinforcement method for preparing nano-covalently linked graphene preforms includes steps such as modified sol preparation, directional cryogenic molding, plasma-activated deposition, microwave covalent bonding, and metal infiltration. Through transition metal catalysis, magnetic field orientation, plasma deposition, and microwave bonding, a tertiary porous structure and a Si-C interface layer are formed, and carbon quantum dots are generated to strengthen the end connections.

Benefits of technology

This approach improves the mechanical properties of graphene preforms, increases conductivity, enhances impregnation compatibility, reduces the need for high-pressure impregnation, minimizes complex pretreatment, and lowers mass production costs.

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Abstract

本发明公开了一种多级协同强化的纳米共价连接石墨烯预制体及其在金属基复合材料中的应用。首先在石墨烯墨水中引入过渡金属改性硅溶胶,通过电磁场辅助冷冻干燥构建取向多孔结构;随后在旋转式沉积炉中采用等离子体活化‑化学气相沉积(PACVD)工艺,以双碳源梯度供气方式在石墨烯片层表面原位生长垂直纳米石墨烯阵列;最后通过微波辐照触发碳硅共价键合。创新性地融合了过渡金属催化‑等离子体活化‑梯度沉积‑微波键合四重协同机制,使预制体压缩强度提升35‑60%,同时实现纳米孔隙定向调控。该预制体用作金属基复合材料增强体时,通过界面过渡层设计使复合材料抗拉强度提高40%以上。
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