一种聚氯乙烯复合固态电解质及其制备方法

By modifying the dual network structure of CePO4 and PCL-based composites, the problems of lithium-ion transport efficiency and interfacial compatibility in polyvinyl chloride solid electrolytes are solved, improving the mechanical properties and electrochemical stability of the battery, making it suitable for high-performance energy storage devices.

CN121790504BActive Publication Date: 2026-07-17QINGHAI UNIV FOR NATITIES

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
QINGHAI UNIV FOR NATITIES
Filing Date
2025-12-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyvinyl chloride solid electrolytes suffer from limited lithium-ion transport efficiency and poor interfacial compatibility with inorganic fillers and electrode materials, leading to issues with battery cycle stability and safety.

Method used

By silanizing CePO4, a PCL-based composite containing dynamic coordination bonds was prepared. This composite was then combined with polyvinyl chloride matrix through multi-component synergistic compounding. A stepwise crosslinking process involving humidity-induced silane hydrolysis condensation and UV curing was employed to construct a dual network structure of covalent crosslinking and dynamic coordination.

Benefits of technology

It achieves simultaneous optimization of electrolyte mechanical properties, ion conduction efficiency and electrochemical stability, improves battery cycle stability and safety, and is suitable for high-performance energy storage devices.

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Abstract

本发明属于固态电解质技术领域,具体涉及一种聚氯乙烯复合固态电解质及其制备方法;其中,聚氯乙烯复合固态电解质,包括以下重量份的原料:30‑50份聚氯乙烯树脂,45‑65份PCL基复合物,3‑8份改性CePO4,20‑35份LiTFSI,3‑6份碳酸丙烯酯;本发明加入的改性CePO4实现了无机填料在聚合物基体中的均匀分散,既增强电解质膜的力学性,又为锂离子传输提供稳定通道;PCL基复合物不仅缓解了聚氯乙烯基体的脆性缺陷,更通过配位键与锂盐的相互作用提升自由锂离子浓度,优化离子传导效率。且分步固化工艺促使体系形成稳定的双重交联网络,大幅提升电解质的电化学稳定性与长期循环可靠性。
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