一种动态膜生物反应器原位电氧化制备分离层的方法

By using electrochemical oxidation technology to modify the biofilm in situ on the surface of the conductive base membrane to form a dense separation layer, the problems of poor pollutant retention and severe membrane fouling in dynamic membrane bioreactors are solved, achieving efficient and stable water treatment results.

CN121800322BActive Publication Date: 2026-07-17INNER MONGOLIA JIUHE ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INNER MONGOLIA JIUHE ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD
Filing Date
2025-12-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Dynamic membrane bioreactors suffer from problems such as poor pollutant retention, unstable effluent quality, and severe membrane fouling due to large-pore base membranes. In particular, the loose biofilm structure makes it easy for the biofilm to detach, making it difficult to form an efficient and stable separation layer.

Method used

In situ modification of biofilms on conductive base film surfaces is achieved through electrochemical oxidation technology. Electrochemical reactions and physicochemical changes are induced by a DC electric field to form a dense functional separation layer. This includes monitoring the transmembrane pressure difference to trigger the electro-oxidation process and removing loose parts through physical cleaning.

Benefits of technology

It significantly improves the retention accuracy and antifouling performance of the separation layer, enhances the stability of effluent water quality, reduces the membrane fouling rate, and is suitable for long-term online operation of dynamic membrane bioreactors.

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Abstract

本发明公开了一种动态膜生物反应器原位电氧化制备分离层的方法,该方法包括:在运行动态膜生物反应器过程中,当监测到跨膜压差达到40‑60 kPa时,停止运行;随后以附着生物膜的导电基膜为阳极,以等面积不锈钢板为阴极,于反应器内原位进行电氧化处理,并同步恢复系统运行;待跨膜压差升至80‑100 kPa时停止,经清洗后即在基膜表面形成稳定的分离层。其原理是利用电氧化作用在基膜表面产生腐蚀位点以增强机械锚固,同时降解松散组分、交联强化生物膜网络结构并引入亲水基团。该方法制备的分离层具有亚微米级截留精度、与基膜结合牢固、亲水性好、抗污染能力强等优点,能显著提升动态膜生物反应器的出水水质和运行稳定性。
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