一种含钨金属氧化物催化剂及其制备方法和应用
The prepared tungsten-containing metal oxide catalyst β-CD-TBAT solved the mass transfer problem in the selective oxidation process of cyclohexene, achieving efficient and stable adipic acid production and meeting the requirements of green chemical industry.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- CHONGQING THREE GORGES UNIV
- Filing Date
- 2026-01-28
- Publication Date
- 2026-07-17
AI Technical Summary
Existing industrial methods for producing adipic acid suffer from severe equipment corrosion, serious environmental pollution, and unstable catalysts, making it difficult to meet the requirements of green chemical development.
A tungsten-containing metal oxide catalyst, β-CD-TBAT, was prepared by reacting β-cyclodextrin with toluenesulfonyl chloride, 2-chloroethylamine hydrochloride, and triethylenediamine. This catalyst was used for the selective oxidation of cyclohexene, solving the mass transfer problem and improving the stability of the catalyst.
It significantly improved the solubility and mass transfer rate of cyclohexene in the aqueous phase, enhanced the yield and purity of adipic acid, and maintained excellent stability and selectivity during recycling, thus reducing operating costs.
Smart Images
Figure CN121819938B_ABST