一种亚碲酸钠溶液电积提取碲的方法

By using composite additives in the alkaline sodium tellurite electrowinning process, the problems of anodic precipitation and cathode purity were solved, achieving efficient extraction and stable production of high-purity tellurium, and improving tellurium recovery rate and product purity.

CN121823489BActive Publication Date: 2026-07-17SHANDONG HUMON SMELTING

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG HUMON SMELTING
Filing Date
2026-01-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The existing alkaline sodium tellurite electrowinning process suffers from severe sodium tellurite precipitation at the anode, limited purity of the cathode tellurite product, and low metal recovery rate, making it difficult to achieve efficient extraction of high-purity tellurite.

Method used

A composite additive consisting of sodium ascorbate, diethylenetriaminepentaacetic acid pentasodium, sodium citrate, and polyvinylpyrrolidone is used to inhibit oxidation reactions in the anodic region, chelate heavy metal impurity ions, and improve the cathode deposition morphology, thereby forming a stable electrodeposition environment.

Benefits of technology

It significantly improved the recovery rate and purity of tellurium, with the purity of cathode tellurium products reaching 99.95%, reduced anode passivation and cell pressure fluctuations, and improved production efficiency and continuity.

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Abstract

本发明公开了一种亚碲酸钠溶液电积提取碲的方法,属于有色金属湿法冶金技术领域。所述方法包括:将粗二氧化碲在60‑90℃下溶于氢氧化钠溶液,配制成含碲200‑240g / L、氢氧化钠90‑110g / L的亚碲酸钠电解液;在电积过程中,同步向电解液中加入由抗坏血酸钠、二乙烯三胺五乙酸五钠、柠檬酸钠和聚乙烯吡咯烷酮组成的复合添加剂。在电流密度40‑60A / m²、电压15‑30V、温度15‑30℃的条件下电积14‑15天。本发明通过复合添加剂的协同作用,显著抑制了阳极区亚碲酸根氧化为不溶性碲酸钠,并强力络合电解液中的重金属杂质离子,从而在保持较优电流效率的同时将碲的直收率提升至90%以上,所得碲锭纯度达到99.95%以上。
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