一种核壳结构碳陶瓷电阻材料、制备方法及电阻

By constructing a core-shell structure and a dual-scale conductive network on the surface of ceramic particles, the problem of conductive path instability in carbon ceramic resistor materials under high current and thermal cycling conditions was solved, thereby improving the stability and reliability of the resistor.

CN121824097BActive Publication Date: 2026-07-17CHINA ELECTRIC POWER RESEARCH INSTITUTE CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA ELECTRIC POWER RESEARCH INSTITUTE CO LTD
Filing Date
2026-03-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing carbon ceramic resistor materials have insufficient stability of the conductive path under high current impact and thermal cycling conditions, resulting in large resistance fluctuations and insufficient reliability.

Method used

A core-shell structured carbon ceramic resistive material is used. A carbon conductive phase is constructed in the ceramic matrix and coated on the surface of the ceramic particles in the form of a coating layer to form a ceramic core-carbon shell structural unit. A two-scale continuous conductive network and gradient pore structure are formed by bidirectional unequal pressure molding and segmented sintering process.

Benefits of technology

It achieves high resistance stability and high reliability under high current and thermal shock conditions, small resistance fluctuation, uniform heat dissipation, and extends the service life of the material.

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Abstract

本发明属于电工陶瓷技术领域,公开了一种核壳结构碳陶瓷电阻材料、制备方法及电阻。该材料以陶瓷基体为主体,碳导电相以包覆层形式均匀分布于陶瓷颗粒表面,构成厚度为5~100nm的“陶瓷核‑碳壳”结构单元,并通过烧结相互连通形成双尺度连续导电网络,同时在材料内部构建由中心至表面逐渐减小的梯度孔隙结构。所述制备方法包括核壳前驱体制备、双向不等压成型以及分段可控烧结步骤,通过界面调控剂辅助碳源定向包覆及拓扑优化烧结,实现碳相形态与导电网络的精准调控。本发明电阻材料电阻波动小,具备高均匀性、优异的大电流冲击承载能力及长热冲击循环寿命,可用于高可靠性合闸电阻,显著提升极端工况下电阻元件的稳定性与使用寿命。
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