一种咔唑衍生物及其制备方法和应用

By using a carbazole derivative with a rigid conjugated large plane as a self-assembled monolayer material, the problems of high cost and poor stability of Spiro-OMeTAD were solved, thus improving the photoelectric conversion efficiency and stability of perovskite solar cells.

CN121851059BActive Publication Date: 2026-07-17SHENZHEN GUANGYIN TECHNOLOGY CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHENZHEN GUANGYIN TECHNOLOGY CO LTD
Filing Date
2026-03-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing perovskite solar cells, the hole transport material Spiro-OMeTAD is expensive and has poor long-term stability, which limits the improvement of device performance. There is a need to develop a self-assembled monolayer material that is simple in structure, low in cost, and has excellent performance.

Method used

Carbazole derivatives with rigid conjugated large planes are used as self-assembled monolayer hole transport materials. Perovskite interface defects are passivated by terminal phosphate anchoring groups, optimizing molecular ordered stacking and improving hole mobility.

Benefits of technology

It significantly improves the photoelectric conversion efficiency and lifespan of perovskite solar cells, reduces interface energy loss, and achieves longer stability.

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Abstract

本发明提供一种咔唑衍生物及其制备方法和应用,本发明以具有刚性共轭大平面的咔唑为母核,优化了分子有序堆积,显著提高了空穴迁移率;末端的磷酸基为锚定基团,可以有效钝化钙钛矿界面缺陷,降低界面处能量损失,可以实现单分子自组装,提高电池性能,其作为自组装单分子层空穴传输材料,使得钙钛矿太阳能电池具有较高的光电转化效率,较长的使用寿命和稳定性。
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