一种强化酸性溶液中钪与铁萃取分离的方法

By introducing fluoride ions into the acidic leachate and controlling the molar ratio of iron to fluorine to form FeF2+ complexes, combined with optimized extraction conditions, the problem of low scandium-iron separation efficiency was solved, achieving efficient scandium recovery and iron-scandium separation, which is suitable for large-scale industrial production.

CN121852744BActive Publication Date: 2026-07-17CENT SOUTH UNIV +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2026-03-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for separating scandium and iron suffer from high costs, low efficiency, and poor separation results in large-scale production. In particular, commercial extractants have low scandium-iron separation coefficients, resulting in long subsequent processing steps and low overall recovery rates of valuable metals.

Method used

Fluoride ions are introduced into the acidic leachate. By controlling the molar ratio of iron to fluorine, a stable FeF2+ complex is formed, which reduces the iron extraction rate while maintaining a high scandium extraction rate. Commercial extractants such as P204 and P507 are used, and extraction conditions such as pH, extractant concentration, phase ratio, and temperature are controlled to carry out multi-stage extraction and separation.

Benefits of technology

It achieves efficient separation of scandium and iron, with high scandium recovery rate, significantly improved iron-scandium separation coefficient, simplified process, strong adaptability, and suitability for industrial applications.

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Abstract

本发明涉及一种强化酸性溶液中钪与铁萃取分离的方法,属于湿法冶金技术领域。本发明创新的往含钪和铁的酸性溶液中加入适量氟离子后,在体系pH的协同作用下,改变了铁离子在溶液中的物种存在形式,降低其与萃取剂的结合反应,使其在萃取过程中保留在水相中,而溶液中钪离子不与氟离子反应,其萃取效率不受氟离子加入的影响。采用本发明优化后的工艺以及其工艺参数能显著降低铁离子在有机相的分配比,从而大幅提高萃取过程中钪与铁的选择性分离系数。本发明无需改变传统的钪萃取工艺流程,钪与铁分离效果更好,对钪与其他常见杂质金属离子(钛、铝等)的萃取分离适应性强,便于工业应用。
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