一种高熵层状双氢氧化物包覆型阻燃抑烟剂及其制备方法与应用

By introducing a high-entropy layered double hydroxide-coated flame retardant and smoke suppressant into TPU, the problems of TPU's flammability and dispersion difficulties are solved, achieving a synergistic improvement in flame retardancy and smoke suppression, and ensuring the safety and processing stability of the material.

CN121873436BActive Publication Date: 2026-07-17UNIV OF SCI & TECH OF CHINA +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
UNIV OF SCI & TECH OF CHINA
Filing Date
2026-03-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Thermoplastic polyurethane (TPU) materials are flammable and have a high heat release rate during combustion, accompanied by melting and dripping, smoke release and harmful gases, which leads to the risk of flame spread and secondary ignition. In addition, existing flame retardants are difficult to disperse in TPU, resulting in poor flame retardant effect.

Method used

A high-entropy layered double hydroxide-coated flame retardant and smoke suppressant is adopted. The smoke suppressant and phosphorus-based flame retardant are chemically bonded by a silane coupling agent to form a core-shell structure. LDH is grown in situ on the surface of the flame retardant using a hydrothermal reaction to form a stable core-shell integrated additive.

Benefits of technology

This approach simultaneously enhances the flame retardancy and smoke suppression properties of TPU materials, reduces heat transfer and smoke particle generation during combustion, improves the processing stability and flame retardant effect of the materials, and avoids the problems of layering and agglomeration in multi-component systems.

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Abstract

本发明公开了一种高熵层状双氢氧化物包覆型阻燃抑烟剂及其制备方法与应用,其中阻燃抑烟剂是以抑烟剂为壳层、磷系阻燃剂为核芯的包裹型阻燃抑烟剂,抑烟剂与磷系阻燃剂之间通过硅烷偶联剂的键接作用以化学键的方式结合;抑烟剂为高熵层状双氢氧化物抑烟剂;硅烷偶联剂为γ‑氨丙基三乙氧基硅烷。通过在磷系阻燃剂表面引入硅烷化反应位点,诱导HELDH在颗粒表面原位生长并形成稳定包覆层,实现抑烟组份与阻燃组份在单颗粒尺度的一体化固定与协同释放。在燃烧阶段,HELDH及其热解产物与磷系组份协同促进成炭并捕集烟尘 / 抑制挥发物释放,实现阻燃性、抑烟性与加工稳定性的同步提升。
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Citation Information

Patent Citations

  • Nano-material covered type flame retardant and preparation method thereof

    CN106957454A