一种发光辅助材料及其制备方法和应用

By using 9-alkyl-9-phenylfluorene as the core light-emitting auxiliary material in OLED display devices to connect aryl and aromatic amine groups, the carrier migration problem between the hole transport layer and the light-emitting layer is solved, improving the device's lifetime and efficiency while reducing the driving voltage.

CN121895173BActive Publication Date: 2026-07-17JILIN OPTICAL & ELECTRONICS MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JILIN OPTICAL & ELECTRONICS MATERIALS CO LTD
Filing Date
2026-03-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing OLED display devices, the localization of carrier migration between the hole transport layer and the light-emitting layer leads to a high hole transport barrier and a low migration rate, which affects the color purity, efficiency, and lifespan of the device.

Method used

A luminescent auxiliary material using 9-alkyl-9-phenylfluorene as the parent core is used to adjust the HOMO and LUMO energy levels by connecting aryl and aromatic amine groups on both sides, thereby reducing the hole injection energy barrier, improving the hole transport rate and luminescence efficiency, and extending the conjugated system to avoid excessive molecular aggregation.

Benefits of technology

It effectively improves the lifespan and luminous efficiency of OLED devices, while reducing the driving voltage and improving the stability and luminous efficiency of the compound.

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Abstract

本发明提供一种发光辅助材料及其制备方法和应用,本发明属于发光材料技术领域,所述发光辅助材料结构式如通式Ⅰ所示,本发明的发光辅助材料以9,9‑苯基烷基芴为母核,在其芴的两侧分别连接芳基与芳胺基团,其中,9,9‑苯基烷基芴具有较高的玻璃化转变温度和量子荧光效率,能够有效提高化合物的稳定性和发光效率,引入给电子基团芳胺可灵活调节最高占有分子轨道和最低未占分子轨道能级,可有效降低空穴注入的能量势垒,提高空穴传输速率与发光效率,同时另一侧连接芳基基团可有效延伸共轭体系,降低分子间的π‑π堆积作用与分子过度聚集导致的荧光猝灭现象,利用该发光辅助材料可有效提升OLED器件的寿命和发光效率同时降低驱动电压。
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