锂电池正极材料及其再生方法

By using a deep eutectic solvent system and coordination precipitation reaction, the problem of material heterogeneity in the regeneration of lithium battery cathode materials was solved, realizing an efficient and simple regeneration process and preparing cathode materials with excellent electrochemical performance.

CN121913562BActive Publication Date: 2026-07-17HUAZHONG UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUAZHONG UNIV OF SCI & TECH
Filing Date
2026-03-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium battery cathode material regeneration processes cannot adapt to waste NCM materials with different degradation levels and ratios, resulting in uneven lithium replenishment, uncontrolled phase transitions, and require complex sorting and high energy consumption, leading to low efficiency.

Method used

By employing a deep eutectic solvent system, including oxalic acid dihydrate and quaternary ammonium salt, lithium is selectively leached and transition metals are simultaneously precipitated under mild conditions through coordination precipitation reaction. The stoichiometric ratio of nickel, cobalt, and manganese is adjusted to prepare a uniform cathode material.

Benefits of technology

This method achieves efficient and selective leaching of lithium and simultaneous fixation of transition metals, shortens the regeneration cycle, reduces costs, avoids complex sorting steps, and improves the electrochemical performance and recycling efficiency of the material.

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Abstract

本发明提供了一种锂电池正极材料及其再生方法,属于废旧电池资源化技术领域。所述方法包括:配制由二水合草酸与甜菜碱盐酸盐和 / 或氯化胆碱形成的深共晶溶剂;将不同配比的废弃NCM正极材料经预处理后,与所述溶剂混合形成选择性浸出体系,通过配位沉淀反应,实现锂的高选择性浸出及过渡金属的草酸盐沉淀;将所得沉淀与锂源混合煅烧,直接再生为特定化学计量比的正极材料。本发明能高效、短时地处理混合废料,工艺流程简洁,金属回收率高,环境友好。
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