一种多功能改性聚羧酸减水剂的制备工艺及其水泥基材料

By introducing hydrophobic side chains into the main chain of polycarboxylate superplasticizer and using ester group inversion to achieve dynamic conversion, the problem of poor compatibility between superplasticizer and hydrophobic agent is solved, and the fluidity and durability of marine cement are improved.

CN121914344BActive Publication Date: 2026-07-17UNIV OF JINAN
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
UNIV OF JINAN
Filing Date
2026-03-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing water-reducing agents and hydrophobic agents have poor compatibility in marine cement, affecting the fluidity and durability of cement materials. Furthermore, traditional shrinkage-reducing agents affect cement hydration and strength.

Method used

A multifunctional modified polycarboxylate superplasticizer is used. By introducing hydrophobic side chains into the main chain of the polycarboxylate superplasticizer and achieving dynamic conversion through ester group inversion, the early water reduction effect and the later hydrophobic protection are ensured, avoiding the mutual restriction between traditional water-reducing agents and hydrophobic agents.

Benefits of technology

The system intelligently switches roles at different stages to maintain the good fluidity and strength of cement-based materials, while constructing a durable hydrophobic system to improve the crack resistance and impermeability of cement materials.

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Abstract

本发明涉及水泥材料技术领域,具体公开一种多功能改性聚羧酸减水剂的制备工艺及其水泥基材料。所述水泥基材料包括如下比例的组分:水泥580~620重量份、矿粉320~340重量份、硅灰55~65重量份、纳米三氧化二铝7~10重量份、水210~230重量份、耐碱玻璃纤维10~15重量份、改性聚羧酸减水剂7~12重量份。本发明通过制备的多功能改性聚羧酸减水剂特定位置基团的“减水‑疏水”带来的动态转换突破了传统减水剂和疏水剂相容性差,相互制约而影响对水泥材料性能改善的问题。
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Citation Information

Patent Citations

  • High-adaptability ester-based modified polycarboxylate superplasticizer as well as preparation and use methods thereof

    CN109679034A

  • Side chain macromonomer, preparation method thereof and low-sensitivity high-adaptability polycarboxylate superplasticizer prepared by using side chain macromonomer

    CN116265494A