一种阻燃聚酰胺材料组分分离循环回收利用方法

By separating BPS and Sb2O3 from flame-retardant polyamide materials through chemical decomposition, the technological gap in the recycling of flame-retardant polyamide materials has been filled, enabling efficient recycling and replacement of market products, and improving resource recycling efficiency and environmental benefits.

CN121914461BActive Publication Date: 2026-07-17BEIJING TECH & BUSINESS UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING TECH & BUSINESS UNIV
Filing Date
2026-01-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, there is insufficient research on the recycling methods of flame-retardant polyamide materials, especially the recycling methods of high-value flame-retardant chemicals BPS and Sb2O3, which leads to environmental pollution and resource waste.

Method used

A chemical decomposition method is used to separate the polyamide matrix by stirring the reaction in an acidic aqueous solution. Subsequently, BPS is dissolved in a haloalkanes and Sb2O3 is separated by adjusting the pH in an alkaline solution. Combined with flash evaporation and drying steps, efficient recovery of BPS and Sb2O3 is achieved.

Benefits of technology

The recovery rate of BPS and Sb2O3 reached over 95%. The resulting recycled materials, Re-BPS and Re-Sb2O3, have performance that is basically consistent with similar products on the market. They can replace market products, improve resource recycling efficiency, and have significant economic and environmental benefits.

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Abstract

本发明公开了一种阻燃聚酰胺材料组分分离循环回收利用方法,旨在解决阻燃聚酰胺废弃塑料制品环境污染问题,提升资源循环利用效率,为工业生产提供高质量的再生高值化学品供给新途径,创新资源再生循环经济发展新范式;所述方法包括:通过酸解的方式,将阻燃聚酰胺材料中的尼龙树脂基体分子结构分解,进而实现溴化聚苯乙烯和增强纤维等添加和填充组分与尼龙树脂基体的分离,再通过溶剂萃取和沉淀析出等分离纯化回收技术获得高品质的溴化聚苯乙烯和三氧化二锑等回收产品,循环用于生产阻燃聚酰胺和阻燃聚酯等阻燃材料,实现高值化学品溴化聚苯乙烯和三氧化二锑的资源化循环回收利用,具备显著的经济效益、环境效益和社会效益,应用前景广阔。
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