一种聚合氯化铝铁絮凝剂及其制备方法与应用

By loading cobalt ferrite onto the surface of nanoporous silica and grafting tartaric acid, an aluminum-iron hydrolysis polymer was constructed, which solved the problem that existing flocculants could not degrade dissolved organic molecules and achieved a highly efficient wastewater treatment effect.

CN121948642BActive Publication Date: 2026-07-17安徽卓德化学科技有限公司

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
安徽卓德化学科技有限公司
Filing Date
2026-02-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyaluminum ferric chloride flocculants cannot effectively degrade organic molecules with stable C-Cl bond structures that exist in a dissolved state, thus affecting the overall removal efficiency of wastewater pollutants.

Method used

Cobalt ferrite was loaded onto the surface of nanoporous silica, and tartaric acid was grafted onto it via an amidation reaction to anchor aluminum-iron hydrolysate polymers, thus constructing composite particles with magnetic, catalytic, and specific adsorption functions.

Benefits of technology

It achieves synergistic removal and efficient separation of heavy metals, recalcitrant organic matter and conventional pollutants, improving wastewater treatment efficiency and avoiding inhibition of microbial activity.

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Abstract

本发明公开了一种聚合氯化铝铁絮凝剂及其制备方法与应用,属于污水处理技术领域,通过共沉淀‑煅烧法,将钴铁氧体负载于纳米介孔二氧化硅表面,得到负载型二氧化硅,再利用硅烷偶联剂KH550进行氨基化改性和酒石酸修饰,得到复合型二氧化硅,最后在酸性条件下将复合型二氧化硅与铝盐、铁盐及过氧化氢共混,通过原位水解聚合与催化氧化协同,在其表面形成并负载聚合氯化铝铁絮凝层,得到聚合氯化铝铁絮凝剂;实现了磁性分离、催化氧化、深度吸附与强化絮凝的四重协同,高效去除悬浮物、溶解性有机物、磷及色度。
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