一种生物质干凝胶及其制备方法和应用

By preparing biomass dry gel materials, a framework is formed by cross-linking quaternized cellulose and chitosan, and fluorinated silicon oxides are attached to the framework. This solves the problem of poor adsorption performance of existing adsorbents for short-chain and ultra-short-chain PFAS, and achieves efficient and sustainable PFAS removal.

CN121949897BActive Publication Date: 2026-07-17WESTLAKE UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
WESTLAKE UNIV
Filing Date
2026-04-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing adsorbent materials have poor adsorption performance for short-chain and ultra-short-chain perfluorinated and polyfluorinated alkyl substances (PFAS), and also suffer from problems such as high cost and poor stability.

Method used

Biomass dry gel material is used, and a framework is formed by cross-linking quaternized cellulose and chitosan. Fluorinated silicon oxygen groups are attached to the framework, and the adsorption performance is optimized by utilizing their electrostatic interaction and steric hindrance.

Benefits of technology

It achieves efficient removal of short-chain and ultra-short-chain PFAS, with good anti-interference ability, structural stability and renewability, reducing raw material costs and improving the sustainability and resource utilization level of materials.

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Abstract

本发明涉及环境功能材料领域,具体涉及一种生物质干凝胶及其制备方法和应用。本发明提供了一种生物质干凝胶,包括骨架和连接在骨架上的氟化硅氧基;所述骨架由季铵化纤维素、壳聚糖和交联剂交联而成。纤维素作为农林副产品的主要成分,具有稳固的层级结构框架和丰富的羟基,易进行功能化修饰;壳聚糖作为富含氨基的天然聚合物,与纤维素的结构具有互补性,可实现交联并产生静电相互作用;同时,在纤维素 / 壳聚糖骨架中引入季铵基与氟化硅氧基,实现了亲水性、表面正电荷密度与亲氟性之间的优化平衡及协同作用,对多种短链 / 超短链PFAS表现出优异的去除性能,且具有出色的抗干扰能力、结构稳定性、良好再生性以及废弃后的优异可回收性。
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