一种水性聚氨酯纸张印刷油墨及其制备方法

By introducing silane coupling agent KH-560 grafted with nanocellulose and dopamine-modified nanotitanium dioxide into waterborne polyurethane ink, combined with PEG-1000 and amino-modified nanoSiO2, the problem of insufficient adhesion of waterborne polyurethane ink on paper was solved, achieving high static adhesion and excellent dynamic performance.

CN121950106BActive Publication Date: 2026-07-17SHANTOU TIANSHENG PACKAGING MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANTOU TIANSHENG PACKAGING MATERIALS CO LTD
Filing Date
2026-03-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Insufficient adhesion of water-based polyurethane inks to paper substrates results in poor printing quality, failing to meet the requirements of actual printing production.

Method used

A ternary cross-linked structure is formed by grafting nanocellulose with silane coupling agent KH-560 and waterborne polyurethane, and a core-shell-crown structure is constructed by modifying nano-titanium dioxide with dopamine and aminosilane. At the same time, PEG-1000 and amino-modified nano-SiO2 are introduced to enhance the interfacial bonding and flexibility between ink and paper.

Benefits of technology

It significantly improves the adhesion performance of water-based polyurethane inks on paper, enhances static adhesion and dynamic folding and abrasion resistance, and prevents micro-cracks from forming in the ink film layer due to interfacial stress concentration under dynamic stress.

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Abstract

本发明公开了一种水性聚氨酯纸张印刷油墨及其制备方法,涉及新型油墨技术领域。制备方法为先将纳米纤维素与硅烷偶联剂KH‑560接枝后分散于水中,再加入水性聚氨酯乳液中进行交联,得改性乳液;将纳米二氧化钛经双氧水活化、多巴胺包覆后与硅烷偶联剂KH‑550反应,得复合改性纳米二氧化钛;将有机颜料、分散剂和水高速分散得色浆;最后将改性乳液与丙烯酸乳液、乙醇、PEG‑1000混合,加入色浆、复合改性纳米二氧化钛、氨基改性纳米二氧化硅及助剂,经高速分散、研磨、过滤即得。本发明制备的油墨附着力强,印刷适性良好。
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