一种具有早期耐水性的水性丙烯酸涂料及其制备方法和应用

By modifying rutile titanium dioxide with a compound silane coupling agent of KH-570 and A-151 and using a dual particle size dispersion process, the problem of insufficient early water resistance of water-based acrylic coatings was solved, and the density and hydrophobicity of the coating film were synergistically improved, making it suitable for outdoor coating construction in areas with variable climates.

CN121950124BActive Publication Date: 2026-07-17BEIJING WAN YUN HUA RUI CHEM CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING WAN YUN HUA RUI CHEM CO LTD
Filing Date
2026-03-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Water-based acrylic coatings have insufficient water resistance in the early stages of outdoor construction, and problems such as whitening, blistering, and peeling are prone to occur before the coating film is fully cured, which limits their application, especially in areas with variable climates.

Method used

Surface modification of rutile titanium dioxide was carried out using a compound silane coupling agent of KH-570 and A-151, and combined with a stepwise dispersion process of dual-particle-size pigments to prepare water-based acrylic coatings with early water resistance. KH-570 provides chemical binding sites and A-151 constructs a hydrophobic siloxane network, thereby improving the interfacial adhesion and hydrophobicity of the coating film.

Benefits of technology

It significantly improves the early water resistance of waterborne acrylic coatings, and the coating density and interfacial hydrophobicity are synergistically enhanced, extending the water molecule penetration path and improving the waterproof performance of the coating.

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Abstract

本发明提供了一种具有早期耐水性的水性丙烯酸涂料及其制备方法和应用,涉及水性涂料技术领域。本发明的涂料包括以下原料:水性丙烯酸乳液50‑60质量份、去离子水10‑20质量份、表面改性粗粒级金红石型钛白粉8‑12质量份、表面改性细粒级金红石型钛白粉5‑10质量份、沉淀硫酸钡6‑10质量份、分散剂0.2‑0.5质量份、消泡剂0.3‑0.5质量份、成膜助剂1.5‑2.5质量份、增稠剂0.2‑0.5质量份、流平剂0.2‑0.5质量份、氨水0.05‑0.15质量份。本发明通过采用KH‑570与A‑151复配硅烷偶联剂对不同粒级金红石型钛白粉进行协同表面改性,并结合双粒径颜料分步分散制备工艺,实现了涂膜致密度与界面疏水性的协同提升,显著改善了水性丙烯酸涂料的早期耐水性,具有广阔的应用前景。
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Citation Information

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