一种用于长距离输送充填的超轻质陶粒支撑剂的制备方法

By modifying the surface of the ceramic proppant and performing segmented oxidation pre-calcination, a gradient structure with a dense outer layer and a porous inner layer is formed. This solves the problems of long-distance transport of low-density ceramic proppant in low-viscosity fracturing fluid and surface integrity and anti-fracture properties under high closure pressure, achieving a balance between high strength and long-term conductivity.

CN121950284BActive Publication Date: 2026-07-17TIANJIN YICHUANG ENERGY TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TIANJIN YICHUANG ENERGY TECH CO LTD
Filing Date
2026-04-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing low-density ceramic proppant cannot simultaneously achieve long-distance transport capability in low-viscosity fracturing fluids and maintain surface integrity, fracture resistance, and long-term conductivity under high closure pressure. Current technologies lack precise process methods for controlling the gradient structure from the surface to the interior.

Method used

After granulation by mixing ultrafine kaolin, α-alumina micro powder and soluble starch, green balls are formed by polyvinyl alcohol binder. Polysilicate precursor sol, pseudoboehmite sol and α-phase nano-alumina isopropanol dispersion are sprayed onto the surface of the green balls in stages. Mullite crystal nuclei powder is then embedded and combined with segmented oxidation pre-calcination to form a gradient structure that is dense on the outside and porous on the inside.

Benefits of technology

It achieves a balance between low density characteristics and high strength and high conductivity, improving the compressive strength and long-term conductivity of ceramsite proppant, and ensuring stability for long-distance transport and high closure pressure in low-viscosity fracturing fluid.

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Abstract

本发明涉及油气资源开发技术领域,具体涉及一种用于长距离输送充填的超轻质陶粒支撑剂的制备方法。该方法包括:制得生球后,先通过分次喷渗聚硅酸盐前驱体溶胶对其进行表面改性,再依次喷加拟薄水铝石溶胶和α相纳米氧化铝分散液,并嵌入莫来石晶核粉末,最后经分段氧化预烧与高温烧结。该方法在支撑剂颗粒表层构建了由莫来石晶体骨架构成的致密强化层,内部则保留多孔轻质结构,从而有效兼顾了低密度、高抗破碎性及长期导流稳定性,尤其适用于低黏度滑溜水压裂液的长距离输送与充填作业。
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